CHAPTER VI

THE AGE OF MODERN CHEMISTRY

The Birth of Modern Chemistry.

§ =71.= Chemistry as distinct from Alchemy and Iatro-chemistry commenced with Robert Boyle (see plate 15), who first clearly recognised that its aim is neither the transmutation of the metals nor the preparation of medicines, but the observation and generalisation of a certain class of phenomena; who denied the validity of the alchemistic view of the constitution of matter, and enunciated the definition of an element which has since reigned supreme in Chemistry; and who enriched the science with observations of the utmost importance. Boyle, however, was a man whose ideas were in advance of his times, and intervening between the iatro-chemical period and the Age of Modern Chemistry proper came the period of the Phlogistic Theory--a theory which had a certain affinity with the ideas of the alchemists.

[Illustration: PLATE 15.

PORTRAIT OF ROBERT BOYLE.

_To face page 94_]]

The Phlogiston Theory.

§ =72.= The phlogiston theory was mainly due to Georg Ernst Stahl (1660-1734). Becher (1635-1682) had attempted to revive the once universally accepted sulphur-mercury-salt theory of the alchemists in a somewhat modified form, by the assumption that all substances consist of three earths--the combustible, mercurial, and vitreous; and herein is to be found the germ of Stahl’s phlogistic theory. According to Stahl, all combustible bodies (including those metals that change on heating) contain _phlogiston_, the principle of combustion, which escapes in the form of flame when such substances are burned. According to this theory, therefore, the metals are compounds, since they consist of a metallic calx (what we now call the “oxide” of the metal) combined with phlogiston; and, further, to obtain the metal from the calx it is only necessary to act upon it with some substance rich in phlogiston. Now, coal and charcoal are both almost completely combustible, leaving very little residue; hence, according to this theory, they must consist very largely of phlogiston; and, as a matter of fact, metals can be obtained by heating their calces with either of these substances. Many other facts of a like nature were explicable in terms of the phlogiston theory, and it became exceedingly popular. Chemists at this time did not pay much attention to the balance; it was observed, however, that metals increased in weight on calcination, but this was “explained” on the assumption that phlogiston possessed negative weight. Antoine Lavoisier (1743-1794), utilising Priestley’s discovery of oxygen (called “dephlogisticated air” by its discoverer) and studying the weight relations accompanying combustion, demonstrated the non-validity of the phlogistic theory[89] and proved combustion to be the combination of the substance burnt with a certain constituent of the air, the oxygen. By this time Alchemy was to all intents and purposes defunct, Boerhave (1668-1738) was the last eminent chemist to give any support to its doctrines, and the new chemistry of Lavoisier gave it a final death-blow. We now enter upon the Age of Modern Chemistry, but we shall deal in this chapter with the history of chemical theory only so far as is necessary in pursuance of our primary object, and hence our account will be very far from complete.

[89] It should be noted, however, that if by the term “phlogiston” we were to understand energy and not some form of matter, most of the statements of the phlogistics would be true so far as they go.

Boyle and the Definition of an Element.

§ =73.= Robert Boyle (1626-1691) had defined an element as a substance which could not be decomposed, but which could enter into combination with other elements giving compounds capable of decomposition into these original elements. Hence, the metals were classed among the elements, since they had defied all attempts to decompose them. Now, it must be noted that this definition is of a negative character, and, although it is convenient to term “elements” all substances which have so far defied decomposition, it is a matter of impossibility to decide what substances are true elements with absolute certainty; and the possibility, however faint, that gold and other metals are of a compound nature, and hence the possibility of preparing gold from the “base” metals or other substances, must always remain. This uncertainty regarding the elements appears to have generally been recognised by the new school of chemists, but this having been so, it is the more surprising that their criticism of alchemistic art was not less severe.

The Stoichiometric Laws.

§ =74.= With the study of the relative weights in which substances combine, certain generalisations or “natural laws” of supreme importance were discovered. These stoichiometric laws, as they are called, are as follows:--

1. “The Law of Constant Proportion”--_The same chemical compound always contains the same elements, and there is a constant ratio between the weights of the constituent elements present._

2. “The Law of Multiple Proportions”--_If two substances combine chemically in more than one proportion, the weights of the one which combine with a given weight of the other, stand in a simple rational ratio to one another._

3. “The Law of Combining Weights”--_Substances combine either in the ratio of their combining numbers, or in simple rational multiples or submultiples of these numbers._ (The weights of different substances which combine with a given weight of some particular substance, which is taken as the unit, are called the combining numbers of such substances with reference to this unit. The usual unit now chosen is 8 grammes of Oxygen.)[90]

[90] In order that these laws may hold good, it is, of course, necessary that the substances are weighed under precisely similar conditions. To state these laws in a more absolute form, we can replace the term “weight” by “mass,” or in preference, “inertia”; for the inertias of bodies are proportional to their weights, providing that they are weighed under precisely similar conditions. For a discussion of the exact significance of these terms “mass” and “inertia,” the reader is referred to the present writer’s _Matter, Spirit and the Cosmos_ (Rider, 1910),