Part 24

THIS X-RAY PHOTOGRAPH IS THAT OF A HAND OF A SOLDIER WOUNDED IN THE GREAT WAR

Note the pieces of shrapnel which are revealed.]

[Illustration: _Photo: National Physical Laboratory._

AN X-RAY PHOTOGRAPH OF A GOLF BALL, REVEALING AN IMPERFECT CORE]

[Illustration: _Reproduced by permission of X-Rays Ltd._

A WONDERFUL X-RAY PHOTOGRAPH

Note the fine details revealed, down to the metal tags of the bootlace and the nails in the heel of the boot.]

§ 4

The Discovery of X-rays

So the story went on from year to year. We shall see in a moment to what it led. Meanwhile the next great step was when, in 1895, Röntgen discovered the X-rays, which are now known to everybody. He was following up the work of Lenard, and he one day covered a "Crookes tube" with some black stuff. To his astonishment a prepared chemical screen which was near the tube began to glow. _The rays had gone through the black stuff; and on further experiment he found that they would go through stone, living flesh, and all sorts of "opaque" substances._ In a short time the world was astonished to learn that we could photograph the skeleton in a living man's body, locate a penny in the interior of a child that had swallowed one, or take an impression of a coin through a slab of stone.

And what are these X-rays? They are not a form of matter; they are not material particles. X-rays were found to be a new variety of _light_ with a remarkable power of penetration. We have seen what the spectroscope reveals about the varying nature of light wave-lengths. Light-waves are set up by vibrations in ether,[2] and, as we shall see, these ether disturbances are all of the same kind; they only differ as regards wave-lengths. The X-rays which Röntgen discovered, then, are light, but a variety of light previously unknown to us; they are ether waves of very short length. X-rays have proved of great value in many directions, as all the world knows, but that we need not discuss at this point. Let us see what followed Röntgen's discovery.

[2] We refer throughout to the "ether" because, although modern theories dispense largely with this conception, the theories of physics are so inextricably interwoven with it that it is necessary, in an elementary exposition, to assume its existence. The modern view will be explained later in the article on Einstein's Theory.

While the world wondered at these marvels, the men of science were eagerly following up the new clue to the mystery of matter which was exercising the mind of Crookes and other investigators. In 1896 Becquerel brought us to the threshold of the great discovery.

Certain substances are phosphorescent--they become luminous after they have been exposed to sunlight for some time, and Becquerel was trying to find if any of these substances give rise to X-rays. One day he chose a salt of the metal uranium. He was going to see if, after exposing it to sunlight, he could photograph a cross with it through an opaque substance. He wrapped it up and laid it aside, to wait for the sun, but he found the uranium salt did not wait for the sun. Some strong radiation from it went through the opaque covering and made an impression of the cross upon the plate underneath. Light or darkness was immaterial. The mysterious rays streamed night and day from the salt. This was something new. Here was a substance which appeared to be producing X-rays; the rays emitted by uranium would penetrate the same opaque substances as the X-rays discovered by Röntgen.

Discovery of Radium

Now, at the same time as many other investigators, Professor Curie and his Polish wife took up the search. They decided to find out whether the emission came from the uranium itself or _from something associated with it_, and for this purpose they made a chemical analysis of great quantities of minerals. They found a certain kind of pitchblende which was very active, and they analysed tons of it, concentrating always on the radiant element in it. After a time, as they successively worked out the non-radiant matter, the stuff began to glow. In the end they extracted from eight tons of pitchblende about half a teaspoonful of something _that was a million times more radiant than uranium_. There was only one name for it--Radium.

That was the starting-point of the new development of physics and chemistry. From every laboratory in the world came a cry for radium salts (as pure radium was too precious), and hundreds of brilliant workers fastened on the new element. The inquiry was broadened, and, as year followed year, one substance after another was found to possess the power of emitting rays, that is, to be radio-active. We know to-day that nearly every form of matter can be stimulated to radio-activity; which, as we shall see, means that _its atoms break up into smaller and wonderfully energetic particles which we call "electrons."_ This discovery of electrons has brought about a complete change in our ideas in many directions.

So, instead of atoms being indivisible, they are actually dividing themselves, spontaneously, and giving off throughout the universe tiny fragments of their substance. We shall explain presently what was later discovered about the electron; meanwhile we can say that every glowing metal is pouring out a stream of these electrons. Every arc-lamp is discharging them. Every clap of thunder means a shower of them. Every star is flooding space with them. We are witnessing the spontaneous breaking up of atoms, atoms which had been thought to be indivisible. The sun not only pours out streams of electrons from its own atoms, but the ultra-violet light which it sends to the earth is one of the most powerful agencies for releasing electrons from the surface-atoms of matter on the earth. It is fortunate for us that our atmosphere absorbs most of this ultra-violet or invisible light of the sun--a kind of light which will be explained presently. It has been suggested that, if we received the full flood of it from the sun, our metals would disintegrate under its influence and this "steel civilisation" of ours would be impossible!

But we are here anticipating, we are going beyond radium to the wonderful discoveries which were made by the chemists and physicists of the world who concentrated upon it. The work of Professor and Mme. Curie was merely the final clue to guide the great search. How it was followed up, how we penetrated into the very heart of the minute atom and discovered new and portentous mines of energy, and how we were able to understand, not only matter, but electricity and light, will be told in the next chapter.

THE DISCOVERY OF THE ELECTRON AND HOW IT EFFECTED A REVOLUTION IN IDEAS

What the discovery of radium implied was only gradually realised. Radium captivated the imagination of the world; it was a boon to medicine, but to the man of science it was at first a most puzzling and most attractive phenomenon. It was felt that some great secret of nature was dimly unveiled in its wonderful manifestations, and there now concentrated upon it as gifted a body of men--conspicuous amongst them Sir J. J. Thomson, Sir Ernest Rutherford, Sir W. Ramsay, and Professor Soddy--as any age could boast, with an apparatus of research as far beyond that of any other age as the _Aquitania_ is beyond a Roman galley. Within five years the secret was fairly mastered. Not only were all kinds of matter reduced to a common basis, but the forces of the universe were brought into a unity and understood as they had never been understood before.

[Illustration: ELECTRIC DISCHARGE IN A VACUUM TUBE

The two ends, marked + and -, of a tube from which nearly all air has been exhausted are connected to electric terminals, thus producing an electric discharge in the vacuum tube. This discharge travels straight along the tube, as in the upper diagram. When a magnetic field is applied, however, the rays are deflected, as shown in the lower diagram. The similarity of the behaviour of the electric discharge with the radium rays (see diagram of deflection of radium rays, _post_) shows that the two phenomena may be identified. It was by this means that the characteristics of electrons were first discovered.]

[Illustration: THE RELATIVE SIZES OF ATOMS AND ELECTRONS

An atom is far too small to be seen. In a bubble of hydrogen gas no larger than the letter "O" there are billions of atoms, whilst an electron is more than a thousand times smaller than the smallest atom. How their size is ascertained is described in the text. In this diagram a bubble of gas is magnified to the size of the world. Adopting this scale, _each atom_ in the bubble would then be as large as a tennis ball.]

[Illustration: IF AN ATOM WERE MAGNIFIED TO THE SIZE OF ST. PAUL'S CATHEDRAL, EACH ELECTRON IN THE ATOM (AS REPRESENTED BY THE CATHEDRAL) WOULD THEN BE ABOUT THE SIZE OF A SMALL BULLET]

[Illustration: ELECTRONS STREAMING FROM THE SUN TO THE EARTH

There are strong reasons for supposing that sun-spots are huge electronic cyclones. The sun is constantly pouring out vast streams of electrons into space. Many of these streams encounter the earth, giving rise to various electrical phenomena.]

§ 5

The Discovery of the Electron

Physicists did not take long to discover that the radiation from radium was very like the radiation in a "Crookes tube." It was quickly recognised, moreover, that both in the tube and in radium (and other metals) the atoms of matter were somehow breaking down.

However, the first step was to recognise that there were three distinct and different rays that were given off by such metals as radium and uranium. Sir Ernest Rutherford christened them, after the first three letters of the Greek alphabet, the Alpha, the Beta, and Gamma rays. We are concerned chiefly with the second group and purpose here to deal with that group only.[3]

[3] The "Alpha rays" were presently recognised as atoms of helium gas, shot out at the rate of 12,000 miles a second.

The "Gamma rays" are _waves_, like the X-rays, not material particles. They appear to be a type of X-rays. They possess the remarkable power of penetrating opaque substances; they will pass through a foot of solid iron, for example.

The "Beta rays," as they were at first called, have proved to be one of the most interesting discoveries that science ever made. They proved what Crookes had surmised about the radiations he discovered in his vacuum tube. But it was _not_ a fourth state of matter that had been found, but a new _property_ of matter, a property common to all atoms of matter. The Beta rays were later christened Electrons. They are

## particles of disembodied electricity, here spontaneously liberated from

the atoms of matter: only when the electron was isolated from the atom was it recognised for the first time as a separate entity. Electrons, therefore, are a constituent of the atoms of matter, and we have discovered that they can be released from the atom by a variety of agencies. Electrons are to be found everywhere, forming part of every atom.

"An electron," Sir William Bragg says, "can only maintain a separate existence if it is travelling at an immense rate, from one three-hundredth of the velocity of light upwards, that is to say, at least 600 _miles a second, or thereabouts_. Otherwise the electron sticks to the first atom it meets." These amazing particles may travel with the enormous velocity of from 10,000 to more than 100,000 miles a second. It was first learned that they are of an electrical nature, because they are bent out of their normal path if a magnet is brought near them. And this fact led to a further discovery: to one of those sensational estimates which the general public is apt to believe to be founded on the most abstruse speculations. The physicist set up a little chemical screen for the "Beta rays" to hit, and he so arranged his tube that only a narrow sheaf of the rays poured on to the screen. He then drew this sheaf of rays out of its course with a magnet, and he accurately measured the shift of the luminous spot on the screen where the rays impinged on it. But when he knows the exact intensity of his magnetic field--which he can control as he likes--and the amount of deviation it causes, and the mass of the moving particles, he can tell the speed of the moving particles which he thus diverts. These particles were being hurled out of the atoms of radium, or from the negative pole in a vacuum tube, at a speed which, in good conditions, reached nearly the velocity of light, i.e. nearly 186,000 miles a second.

Their speed has, of course, been confirmed by numbers of experiments; and another series of experiments enabled physicists to determine the size of the particles. Only one of these need be described, to give the reader an idea how men of science arrived at their more startling results.

Fog, as most people know, is thick in our great cities because the water-vapour gathers on the particles of dust and smoke that are in the atmosphere. This fact was used as the basis of some beautiful experiments. Artificial fogs were created in little glass tubes, by introducing dust, in various proportions, for supersaturated vapour to gather on. In the end it was possible to cause tiny drops of rain, each with a particle of dust at its core, to fall upon a silver mirror and be counted. It was a method of counting the quite invisible particles of dust in the tube; and the method was now successfully applied to the new rays. Yet another method was to direct a slender stream of the particles upon a chemical screen. The screen glowed under the cannonade of

## particles, and a powerful lens resolved the glow into distinct sparks,

which could be counted.

In short, a series of the most remarkable and beautiful experiments, checked in all the great laboratories of the world, settled the nature of these so-called rays. They were streams of particles more than a thousand times smaller than the smallest known atom. The mass of each

## particle is, according to the latest and finest measurements 1/1845 of

that of an atom of hydrogen. The physicist has not been able to find any character except electricity in them, and the name "electrons" has been generally adopted.

The Key to many Mysteries

The Electron is an atom, of disembodied electricity; it occupies an exceedingly small volume, and its "mass" is entirely electrical. These electrons are the key to half the mysteries of matter. Electrons in rapid motion, as we shall see, explain what we mean by an "electric current," not so long ago regarded as one of the most mysterious manifestations in nature.

"What a wonder, then, have we here!" says Professor R. K. Duncan. "An innocent-looking little pinch of salt and yet possessed of special properties utterly beyond even the fanciful imaginings of men of past time; for nowhere do we find in the records of thought even the hint of the possibility of things which we now regard as established fact. This pinch of salt projects from its surface bodies [i.e. electrons] possessing the inconceivable velocity of over 100,000 miles a second, a velocity sufficient to carry them, if unimpeded, five times around the earth in a second, and possessing with this velocity, masses a thousand times smaller than the smallest atom known to science. Furthermore, they are charged with negative electricity; they pass straight through bodies considered opaque with a sublime indifference to the properties of the body, with the exception of its mere density; they cause bodies which they strike to shine out in the dark; they affect a photographic plate; they render the air a conductor of electricity; they cause clouds in moist air; they cause chemical action and have a peculiar physiological action. Who, to-day, shall predict the ultimate service to humanity of the beta-rays from radium!"

§ 6

THE ELECTRON THEORY, OR THE NEW VIEW OF MATTER

The Structure of the Atom

There is general agreement amongst all chemists, physicists, and mathematicians upon the conclusions which we have so far given. We know that the atoms of matter are constantly--either spontaneously or under stimulation--giving off electrons, or breaking up into electrons; and they therefore contain electrons. Thus we have now complete proof of the independent existence of atoms and also of electrons.

When, however, the man of science tries to tell us _how_ electrons compose atoms, he passes from facts to speculation, and very difficult speculation. Take the letter "o" as it is printed on this page. In a little bubble of hydrogen gas no larger than that letter there are _trillions_ of atoms; and they are not packed together, but are circulating as freely as dancers in a ball-room. We are asking the physicist to take one of these minute atoms and tell us how the still smaller electrons are arranged in it. Naturally he can only make mental pictures, guesses or hypotheses, which he tries to fit to the facts, and discards when they will _not_ fit.

At present, after nearly twenty years of critical discussion, there are two chief theories of the structure of the atom. At first Sir J. J. Thomson imagined the electrons circulating in shells (like the layers of an onion) round the nucleus of the atom. This did not suit, and Sir E. Rutherford and others worked out a theory that the electrons circulated round a nucleus rather like the planets of our solar system revolving round the central sun. Is there a nucleus, then, round which the electrons revolve? The electron, as we saw, is a disembodied atom of electricity; we should say, of "negative" electricity. Let us picture these electrons all moving round in orbits with great velocity. Now it is suggested that there is a nucleus of "positive" electricity attracting or pulling the revolving electrons to it, and so forming an equilibrium, otherwise the electrons would fly off in all directions. This nucleus has been recently named the proton. We have thus two electricities in the atom: the positive = the nucleus; the negative = the electron. Of recent years Dr. Langmuir has put out a theory that the electrons do not _revolve round_ the nucleus, but remain in a state of violent agitation of some sort at fixed distances from the nucleus.

[Illustration: PROFESSOR SIR J. J. THOMSON

Experimental discoverer of the electronic constitution of matter, in the Cavendish Physical Laboratory, Cambridge. A great investigator, noted for the imaginative range of his hypotheses and his fertility in experimental devices.]

[Illustration: _From the Smithsonian Report_, 1915.

ELECTRONS PRODUCED BY PASSAGE OF X-RAYS THROUGH AIR

A photograph clearly showing that electrons are definite entities. As electrons leave atoms they may traverse matter or pass through the air in a straight path The illustration shows the tortuous path of electrons resulting from collision with atoms.]

[Illustration: MAGNETIC DEFLECTION OF RADIUM RAYS

The radium rays are made to strike a screen, producing visible spots of light. When a magnetic field is applied the rays are seen to be deflected, as in the diagram. This can only happen if the rays carry an electric charge, and it was by experiments of this kind that we obtained our knowledge respecting the electric charges carried by radium rays.]

[Illustration: _Reproduced by permission of "Scientific American."_

PROFESSOR R. A. MILLIKAN'S APPARATUS FOR COUNTING ELECTRONS]

But we will confine ourselves here to the facts, and leave the contending theories to scientific men. It is now pretty generally accepted that an atom of matter consists of a number of electrons, or charges of negative electricity, held together by a charge of positive electricity. It is not disputed that these electrons are in a state of violent motion or strain, and that therefore a vast energy is locked up in the atoms of matter. To that we will return later. Here, rather, we will notice another remarkable discovery which helps us to understand the nature of matter.

A brilliant young man of science who was killed in the war, Mr. Moseley, some years ago showed that, when the atoms of different substances are arranged in order of their weight, _they are also arranged in the order of increasing complexity of structure_. That is to say, the heavier the atom, the more electrons it contains. There is a gradual building up of atoms containing more and more electrons from the lightest atom to the heaviest. Here it is enough to say that as he took element after element, from the lightest (hydrogen) to the heaviest (uranium) he found a strangely regular relation between them. If hydrogen were represented by the figure one, helium by two, lithium three, and so on up to uranium, then uranium should have the figure ninety-two. This makes it probable that there are in nature ninety-two elements--we have found eighty-seven--and that the number Mr. Moseley found is the number of electrons in the atom of each element; that is to say, the number is arranged in order of the atomic numbers of the various elements.

§ 7

The New View of Matter

Up to the point we have reached, then, we see what the new view of Matter is. Every atom of matter, of whatever kind throughout the whole universe, is built up of electrons in conjunction with a nucleus. From the smallest atom of all--the atom of hydrogen--which consists of one electron, rotating round a positively charged nucleus, to a heavy complicated atom, such as the atom of gold, constituted of many electrons and a complex nucleus, _we have only to do with positive and negative units of electricity_. The electron and its nucleus are

## particles of electricity. All Matter, therefore, is nothing but a

manifestation of electricity. The atoms of matter, as we saw, combine and form molecules. Atoms and molecules are the bricks out of which nature has built up everything; ourselves, the earth, the stars, the whole universe.

But more than bricks are required to build a house. There are other fundamental existences, such as the various forms of energy, which give rise to several complex problems. And we have also to remember, that there are more than eighty distinct elements, each with its own definite type of atom. We shall deal with energy later. Meanwhile it remains to be said that, although we have discovered a great deal about the electron and the constitution of matter, and that while the physicists of our own day seem to see a possibility of explaining positive and negative electricity, the nature of them both is unknown. There exists the theory that the particles of positive and negative electricity, which make up the atoms of matter, are points or centres of disturbances of some kind in a universal ether, and that all the various forms of energy are, in some fundamental way, aspects of the same primary entity which constitutes matter itself.