XXXVII.

FIRST EXCITATION OF COLOUR.

501.

In the division of physical colours, where semi-transparent mediums were considered, we saw colours antecedently to white and black. In the present case we assume a white and black already produced and fixed; and the question is, how colour can be excited in them?

502.

Here, too, we can say, white that becomes darkened or dimmed inclines to yellow; black, as it becomes lighter, inclines to blue.--Note U.

503.

Yellow appears on the active (plus) side, immediately in the light, the bright, the white. All white surfaces easily assume a yellow tinge; paper, linen, wool, silk, wax: transparent fluids again, which have a tendency to combustion, easily become yellow; in other words they easily pass into a very slight state of semi-transparence.

504.

So again the excitement on the passive side, the tendency to obscure, dark, black, is immediately accompanied with blue, or rather with a reddish-blue. Iron dissolved in sulphuric acid, and much diluted with water, if held to the light in a glass, exhibits a beautiful violet colour as soon as a few drops only of the infusion of gall-nuts are added. This colour presents the peculiar hues of the dark topaz, the _orphninon_ of a burnt-red, as the ancients expressed it.

505.

Whether any colour can be excited in the pure earths by the chemical operations of nature and art, without the admixture of metallic oxydes, is an important question, generally, indeed, answered in the negative. It is perhaps connected with the question--to what extent changes may be produced in the earths through oxydation?

506.

Undoubtedly the negation of the above question is confirmed by the circumstance that wherever mineral colours are found, some trace of metal, especially of iron, shows itself; we are thus naturally led to consider how easily iron becomes oxydised, how easily the oxyde of iron assumes different colours, how infinitely divisible it is, and how quickly it communicates its colour. It were to be wished, notwithstanding, that new experiments could be made in regard to the above point, so as either to confirm or remove any doubt.

507.

However this may be, the susceptibility of the earths with regard to colours already existing is very great; aluminous earth is thus

## particularly distinguished.

508.

In proceeding to consider the metals, which in the inorganic world have the almost exclusive prerogative of appearing coloured, we find that, in their pure, independent, natural state, they are already distinguished from the pure earths by a tendency to some one colour or other.

509.

While silver approximates most to pure white,--nay, really represents pure white, heightened by metallic splendour,--steel, tin, lead, and so forth, incline towards pale blue-grey; gold, on the other hand, deepens to pure yellow, copper approaches a red hue, which, under certain circumstances, increases almost to bright red, but which again returns to a yellow golden colour when combined with zinc.

510.

But if metals in their pure state have so specific a determination towards this or that exhibition of colour, they are, through the effect of oxydation, in some degree reduced to a common character; for the elementary colours now come forth in their purity, and although this or that metal appears to have a particular tendency to this or that colour, we find some that can go through the whole circle of hues, others, that are capable of exhibiting more than one colour; tin, however, is distinguished by its comparative inaptitude to become coloured. We propose to give a table hereafter, showing how far the different metals can be more or less made to exhibit the different colours.

511.

When the clean, smooth surface of a pure metal, on being heated, becomes overspread with a mantling colour, which passes through a series of appearances as the heat increases, this, we are persuaded, indicates the aptitude of the metal to pass through the whole range of colours. We find this phenomenon most beautifully exhibited in polished steel; but silver, copper, brass, lead, and tin, easily present similar appearances. A superficial oxydation is probably here taking place, as may be inferred from the effects of the operation when continued, especially in the more easily oxydizable metals.

512.

The same conclusion may be drawn from the fact that iron is more easily oxydizable by acid liquids when it is red hot, for in this case the two effects concur with each other. We observe, again, that steel, accordingly as it is hardened in different stages of its colorification, may exhibit a difference of elasticity: this is quite natural, for the various appearances of colour indicate various degrees of heat.[1]

513.

If we look beyond this superficial mantling, this pellicle of colour, we observe that as metals are oxydized throughout their masses, white or black appears with the first degree of heat, as may be seen in white lead, iron, and quicksilver.

514.

If we examine further, and look for the actual exhibition of colour, we find it most frequently on the _plus_ side. The mantling, so often mentioned, of smooth metallic surfaces begins with yellow. Iron passes presently into yellow ochre, lead from white lead to massicot, quicksilver from æthiops to yellow turbith. The solutions of gold and platinum in acids are yellow.

515.

The exhibitions on the _minus_ side are less frequent. Copper slightly oxydized appears blue. In the preparation of Prussian-blue, alkalis are employed.

516.

Generally, however, these appearances of colour are of so mutable a nature that chemists look upon them as deceptive tests, at least in the nicer gradations. For ourselves, as we can only treat of these matters in a general way, we merely observe that the appearances of colour in metals may be classed according to their origin, manifold appearance, and cessation, as various results of oxydation, hyper-oxydation, ab-oxydation, and de-oxydation.[2]

[1] See par. 478.

[2] As these terms are afterwards referred to (par. 525), it was necessary to preserve them.