Part 38
Some tanners, now that the hides are set flat, put them in suspension again before laying away; the method has its advantages, but is not general. The goods are generally laid away immediately. The layer liquors consist of leached liquors from the fishings, strengthened with either chestnut or oakwood extract, or a mixture of the two. The first layer is made up to, say, 60° barkometer in this way, and as the hides are laid down they are sprinkled with fresh tanning material, and remain undisturbed for about one week. The second layer is a 70° barkometer liquor, the hides are again sprinkled and allowed to lie for perhaps two weeks. The third may be 80° barkometer and the fourth 90°, the goods being "dusted" as before, and lying undisturbed for perhaps three or four weeks respectively. Some tanners give more layers, and some give less, some more or less time, or greater or lesser strengths of liquor, but this tannage is a typical modern one.
As regards "dusting" material, for mellow leather, mellow materials are required, such as myrobalans being the mellowest and mimosa bark the most astringent of those used in this connexion. For harder leather, as sole leather, a much smaller quantity of myrobalans is used, if any at all, a fair quantity of mimosa bark as a medium, and much valonia, which deposits a large amount of bloom, and is of great astringency. About 3 to 4 cwt. of a judicious mixture is used for each pit, the mellower material predominating in the earlier liquors and the most astringent in the later liquors.
The tanning is now finished, and the goods are handled out of the pits, brushed free from dusting material, washed up in weak liquor, piled and allowed to drip for 2 or 3 days so that the tan may become set.
_Finishing._--From this stage the treatment of sole leather differs from that of harness, belting and mellower leathers. As regards the first, it will be found on looking at the dripping pile of leather that each butt is covered with a fawn-coloured deposit, known technically as "bloom"; this disguises the under colour of the leather, just like a coat of paint. The theory of the formation of this bloom is this. Strong solutions of tannin, such as are formed between the hides from dusting materials, are not able to exist for long without decomposition, and consequently the tannin begins to condense, and forms other acids and insoluble anhydrides; this insoluble matter separates in and on the leather, giving weight, firmness, and rendering the leather waterproof. It is known technically as bloom and chemically as ellagic acid.
After dripping, the goods are scoured free from surface bloom in a Wilson scouring machine, and are then ready for bleaching. There are several methods by which this is effected, or, more correctly several materials or mixtures are used, the method of application being the same, viz. the goods are "vatted" (steeped) for some hours in the bleaching mixture at a temperature of 110° F. The mixture may consist of either sumach and a light-coloured chestnut extract made to 110° barkometer, and 110° F., or some bleaching extract made for the purpose, consisting of bisulphited liquid quebracho, which bleaches by reason of the free sulphurous acid it contains. The former method is best (though more expensive), as it removes less weight, and the light shade of colour is more permanent than that obtained by using bisulphited extracts.
After the first vatting the goods are laid up in pile to drip; meanwhile the liquor is again heated, and they are then returned for another twenty-four hours, again removed and allowed to drip for 2 to 3 days, after which they are oiled with cod oil on the grain and hung up in the sheds to dry in the dark. When they have dried to an india-rubber-like condition, they are piled and allowed to heat slightly until a greyish "bloom" rises to the surface, they are then set out and stretched in a Wilson scouring machine; using brass slickers instead of the stone ones used for scouring, "pinned" over by hand (with the three-edged instrument seen in c, fig. 4, and known as a "pin") to remove any bloom not removed by the machine, oiled and dried. When of a damp even colour they are "rolled on" between two heavy rollers like a wringing machine, the pressure being applied from above, hung up in the dark sheds again until the uneven colour so produced has dried in, and then "rolled off" through the same machine, the pressure being applied from below. They are now dried right out, brushed on the grain to produce a slight gloss, and are finished.
As regards the finishing of harness leather, &c., the goods, after thorough dripping for a day or two, are brushed, lightly scoured, washed up in hot sumach and extract to improve the colour, and are again laid up in pile for two days; they are then given a good coat of cod oil, sent to the sheds, and dried right out. Only sufficient scouring is given to clean the goods, the object of the tanner being to leave as much weight in as possible, although all this superfluous tan has to be washed out by the currier before he can proceed.
_Currying._--When the goods are dried from the sheds they are purchased by the currier. If, as is often the case, the tanner is his own currier, he does not tan the goods so heavily, or trouble about adding superfluous weight, but otherwise the after processes, the art of the currier, are the same.
Currying consists of working oil and grease into the leather to render it pliable and increase its strength. It was once thought that this was a mere physical effect produced by the oil, but such is not the case. Currying with animal oils is a second tannage in itself; the oils oxidize in the fibres and produce aldehydes, which are well-known tanning agents; and this double tannage renders the leather very strong. Then there is the lubricating effect, a very important physical action so far as the strength of the leather is concerned. Mineral oils are much used, but they do not oxidize to aldehydes, or, for the matter of that, to anything else, as they are not subject to decomposition. They, therefore, produce no second tannage, and their action is merely the physical one of lubrication, and this is only more or less temporary, as, except in the case of the heavier greases, they slowly evaporate. Where animal fats and oils are used, the longer the goods are left in contact with the grease the better and stronger will be the leather.
In the "Einbrennen" process (German for "burning in"), the hides are thoroughly scoured, and when dry are dipped into hot grease, which is then allowed to cool; when it is nearly set the goods are removed and set out. This process is not much used in Great Britain.
In hand-stuffing belting butts the goods are first thoroughly soaked in water to which has been added some soda, and then scoured and stretched by machine. They are then lightly shaved, to take off the loose flesh and thin the neck. The whole of the mechanically deposited tannin is removed by scouring, to make room for the grease, and they are then put into a sumach vat of 40° barkometer to brighten the colour, horsed up to drip, and set out. If any loading, to produce fictitious weight, is to be done, it is done now, by brushing the solution of either epsom salts, barium chloride or glucose, or a mixture, into the flesh, and laying away in pile for some days to allow of absorption, when, perhaps, another coat is given. Whether this is done or not, the goods are hung up until "tempered" (denoting a certain degree of dryness), and then treated with dubbin. This is manufactured by melting down tallow in a steam-jacketed pan, and adding cod oil, the mixture being stirred continually; when quite clear, it is cooled as rapidly as possible by running cold water through the steam pan, the stirring being continued until it has set. The tempered leather having been set out on a glass table, to which the flesh side adheres, is given a thin coat of the dubbin on the grain, turned, set out on the flesh, and given a thick coat of dubbin. Then it is hung up in a wind shed, and as the moisture dries out the grease goes in. After two or three days the goods are "set out in grease" with a brass slicker, given a coat of dubbin on the grain slightly thicker than the first coat, then flesh dubbined, a slightly thinner coat being applied than at first, and stoved at 70° F. The grease which is slicked off when "setting out in grease" is collected and sold. After hanging in the warm stove for 2 or 3 days the butts are laid away in grease for a month; they are then slicked out tight, flesh and grain, and buck tallowed. Hard tallow is first rubbed on the grain, when a slight polish is induced by rubbing with the smoothed rounded edge of a thick slab of glass; they are then hung up in the stove or stretched in frames to dry. A great deal of stuffing is now carried out by drumming the goods in hot hard fats in previously heated drums; and in modern times the tedious process of laying away in grease for a month is either left undone altogether or very considerably shortened.
In the tanning and dressing of the commoner varieties of kips and dried hides, the materials used are of a poorer quality, and the time taken for all processes is cut down, so that whereas the time taken to dress the better class of leather is from 7 to 10 months, and in a few cases more, these cheaper goods are turned out in from 3½ to 5 months.
A considerable quantity of the leather which reaches England, such as East India tanned kips, Australian sides, &c., is bought up and retanned, being sold then as a much better-class leather. The first operation with such goods is to "strip" them of any grease they may contain, and part of their original tannage. This is effectually carried out by first soaking them thoroughly, laying them up to drip, and drumming for half an hour in a weak solution of soda; they are then washed by drumming in plenty of water, the water is run off and replaced by very weak sulphuric acid to neutralize any remaining soda; this is in turn run off and replaced by weak tan liquor, and the goods are so tanned by drumming for some days in a liquor of gradually increasing strength. The liquor is made up as cheaply as possible with plenty of solid quebracho and other cheap extract, which is dried in with, perhaps, glucose, epsom salts, &c. to produce weight. Sometimes a better tannage is given to goods of fair quality, in which they are, perhaps, started in the drum and finished in layers, slightly better materials being used all through, and a longer time taken to complete the tannage.
The tannage of dressing hides for bag and portmanteau work is rather different from the other varieties described, in that the goods, after having had a rather longer liming, are "bated" or "puered."
Bating consists of placing the goods in a wheel or paddle with hen or pigeon excrement, and paddling for from a few hours to 2 or 3 days. In puering, dog manure is used, and this being rather more active, the process does not take so long. This bating or puering is carried out in warm liquors, and the actions involved are several. From a practical point of view the action is the removal of the lime and the solution of the hair sacs and a certain amount of interfibrillar substance. In this way the goods are pulled down to a soft flaccid condition, which allows of the removal of short hair, hair sacs and other filth by scudding with an unhairing knife upon the beam. The lime is partially taken into solution and partially removed mechanically during the scudding. A large quantity of hide substance, semi-soluble and soluble, is lost by being pressed out, but this matters little, as for dressing work, area, and not weight, is the main consideration. Theoretically the action is due to bacteria and bacterial products (organized ferments and enzymes), unorganized ferments or vegetable ferments like the yeast ferment, such as pancreadine, pepsin, &c. and chemicals, such as ammonium and calcium salts and phosphates, all of which are present in the manure. The evolved gases also play their part in the action.
There are several bates upon the market as substitutes for dung bate. A most popular one was the American "Tiffany" bate, made by keeping a weak glue solution warm for some hours and then introducing a piece of blue cheese to start fermentation; when fermenting, glucose was added, and the bate was then ready for work. This and all other bates have been more or less supplanted by "erodin," discovered after years of research by Mr Wood (Nottingham) and Drs Popp and Becker (Vienna). This is an artificial bate, containing the main constituents of the dung bate. It is supplied in the form of a bag of nutrient material for bacteria to thrive on and a bottle of bacterial culture. The nutrient material is dissolved in water and the bacterial culture added, and after allowing the mixture to get working it is ready for use. Many tons of this bate are now being used per annum. Its advantages are: (1) that it is clean, (2) that it is under perfect control, and (3) that stains and bate burns, which so often accompany the dung bate, are absolutely absent. Bate burns are caused by not filtering the dung bate through coarse sacking before use. The accumulation of useless solid matter settles on the skins if they are not kept well in motion, causing excessive action in these places.
After pulling down the goods to a soft, silky condition by bating or puering, it is necessary, after scudding, to plump them up again and bring them into a clean and fit condition for receiving the tan. This is done by "drenching" in a bran drench. A quantity of bran is scalded and allowed to ferment. When the fermentation has reached the proper stage the goods are placed, together with the bran liquor, in a suitable pit or vat, and are allowed to remain until they have risen three times; this rising to the surface is caused by the gaseous products of the fermentation being caught by the skin. The plumping action of the bran is due to the acids produced during fermentation and also in part to the gases, and the cleansing action is due to the mechanical action of the
## particles of bran rubbing against the grain of the skins. After
drenching, the goods are washed free from bran, and are ready for the tanning process.
Drenching, now that all kinds of acids are available, is not so much used for heavy hides as for light skins, it being found much more convenient and cheaper to use acids. In fact, bating and puering are being gradually replaced by acid baths in the case of heavy leathers, the process being carried out as deliming for sole leather, only much more thoroughly in the case of dressing leather.
The tanning of dressing hides, which are not rounded into butts and offal, is briefly as follows. They first enter a series of colouring pits or suspenders, and then a series of handlers, by which time they should be plump and coloured through; in this condition they are split either by means of a union or band-knife splitting machine (fig. 7).
[Illustration: FIG. 7.--Band Knife Splitting Machine.]
This latter is the most popular machine, and consists essentially of an endless band knife _a_, which revolves at considerable speed with its cutting edges close to the sides of a pair of rollers through which the leather is fed and pressed against the knife. The lower of these rollers is made of short segments or rings, each separately capable of yielding so as to accommodate itself to the unequal thicknesses of various parts of a hide. The thickness of the leather to be cut is gauged to the utmost minuteness by means of the hand screws _b b_ which raise or lower the upper roller. The knife edge of the cutter is kept keen by rubbing against revolving emery wheels _c_ as it passes round. So delicately can this machine effect its work that slices of leather uniform throughout and as thin as paper can be easily prepared by it, and by its aid it is quite common to split hides into as many as three useful splits.
The dressing hides are usually split in two. Here we will leave the split (flesh) for a time and continue with the treatment of the grain. After splitting, they enter another series of handlers, are then piled up for a day or two, and thrown into a large drum with sumach mixed to a paste with hot water and a light-coloured extract. They are drummed in this for one hour to brighten and mellow the grain, washed up in tepid liquor, piled for two days, and drummed with cod oil or some other suitable oil or mixture; they are now piled for a day or two to absorb, dried out, flattened on the grain, and flesh folded.
The splits are rinsed up in old sumach liquor and drummed with cheap extracts and adulterants, such as size, glucose, barium chloride, epsom salts, &c. after which they are piled up to drain, dried to a "sammied" condition, rolled to make firm, and dried right out.
In the dressing hide tannage very mellow materials are used. Gambier and myrobalans form the main body of the tannage, together with a little quebracho extract, mimosa bark, sumach and extracts.
_Upper Leather._--Under the head of upper leather are included the thin, soft and pliable leathers, which find their principal, but by no means exclusive, application in making the uppers of boots and shoes, which may be taken as a type of a class of leathers. They are made from such skins as East Indian kips, light cow and horse hides, thin split hides, such as those described under dressing leather, but split rather thinner, and calf. The preparatory dressing of such skins and the tanning operations do not differ essentially from those already described. In proportion to the thinness of the skin treated, the processes are more rapidly finished and less complex, the tannage is a little lighter, heavy materials such as valonia being used sparsely if at all. Generally speaking, the goods have a longer and mellower liming and bating, the lime being more thoroughly removed than for the leathers previously described, to produce greater pliability, and everything must tend in this direction. The heavier hides and kips are split as described under dressing leather, and then tanned right out.
_Currying of the Lighter Leathers._--The duty of the currier is not solely directed towards heavier leathers; he is also entrusted with the dressing and fitting of the lighter leathers for the shoemaker, coachbuilder, saddler, &c. He has to pare the leather down and reduce inequalities in thickness, to impregnate it with fatty matter in order to render it soft and pliable, and to give it such a surface dressing, colour and finish as will please the eye and suit the purposes of its consumers. The fact that machinery is used by some curriers for nearly every mechanical operation, while others adhere to the manual system, renders it almost impossible to give in brief an outline of operations which will be consistent with any considerable number of curriers.
[Illustration: FIG 8.--Currying Knife.]
The following may be taken as a typical modern dressing of waxed calf or waxed kips. The goods are first of all soaked down and brought to a "sammied" condition for shaving. In the better-class leathers hand-shaving is still adhered to, as it is maintained that the drag of the shaving machine on the leather causes the "nap" finish to be coarser. Hand-shaving is carried out on a beam or strong frame of wood, supporting a stout plank faced with lignum vitae, and set vertically, or nearly so. The knife (fig. 8) is a double-edged rectangular blade about 12 in. by 5 in., girded on either side along its whole length and down the centre with two bars 3 in. wide, leaving each blade protruding 1 in. beyond them; it has a straight handle at one end and a cross handle at the other in the plane of the blade. The edges of this knife are first made very keen, and are then turned over so as to form a wire edge, by means of the thicker of the two straight steel tools shown in fig. 9. The wire edge is preserved by drawing the thinner of the two steel tools along the interior angle of the wire edge and then along the outside of the turnover edge. The skin being thrown flesh uppermost over the vertical beam, the shaver presses his body against it, and leaning over the top holds the knife by its two handles almost at right angles to the leather, and proceeds to shave it by a scraping stroke downwards which the wire edge, being set at right angles to the knife and almost parallel with the skin, turns into a cut. The skin is shifted so as to bring all parts under the
## action of the knife, the shaver frequently passing a fold between his