part Mix
. Keep in a closely stoppered jar or box. Strew in places affected by flies.
«Fly Essences.»—
I.—Eucalyptol 10 parts Bergamot oil 3 parts Acetic ether 10 parts Cologne water 50 parts Alcohol, 90 per cent 100 parts
Mix. One part of this “essence” is {422} to be added to 10 parts of water and sprayed around the rooms frequently.
II.—Eucalyptol 10 parts Acetic ether 5 parts Cologne water 40 parts Tincture of insect powder (1:5) 50 parts
«REMEDIES AGAINST HUMAN PARASITES:»
By weight
I.—Yellow wax 85 parts Spermaceti 60 parts Sweet oil 500 parts
Melt and add:
Boiling distilled water 150 parts
After cooling add:
Clove oil 2 parts Thyme oil 3 parts Eucalyptus oil 4 parts
II.—Bay oil, pressed 100 parts Acetic ether 12 parts Clove oil 4 parts Eucalyptus oil 3 parts
«For Head Lice in Children.»—One of the best remedies is a vinegar of sabadilla. This is prepared as follows: Sabadilla seed, 5 parts; alcohol, 5 parts; acetic acid, 9 parts; and water, 36 parts. Macerate for 3 days, express and filter. The directions are: Moisten the scalp and hair thoroughly at bedtime, binding a cloth around the head, and let remain overnight. If there are any sore spots on the scalp, these should be well greased before applying the vinegar.
«To Exterminate Mites.»—Mix together 10 parts of naphthalene, 10 parts of phenic acid, 5 parts of camphor, 5 parts of lemon oil, 2 parts of thyme oil, 2 parts of oil of lavender, and 2 parts of the oil of juniper, in 500 parts of pure alcohol.
«Vermin Killer.»—
Sabadilla, powder 2 av. ounces Acetic acid 1/2 fluidounce Wood alcohol 2 fluidounces Water sufficient to make 16 fluid ounces.
Mix the acetic acid with 14 fluidounces of water and boil the sabadilla in this mixture for 5 to 10 minutes, and when nearly cold add the alcohol, let stand, and decant the clear solution and bottle.
Directions: Shake the bottle and apply to the affected parts night and morning.
«INSECTICIDES FOR PLANTS.»
Two formulas for insecticides with especial reference to vermin which attack plants:
I.—Kerosene 2 gallons Common soap 1/2 pound Water 1 gallon
Heat the solution of soap, add it boiling hot to the kerosene and churn until it forms a perfect emulsion. For use upon scale insects it is diluted with 9 parts of water; upon other ordinary insects with 15 parts of water, and upon soft insects, like plant lice, with from 20 to 25 parts of water.
For lice, etc., which attack the roots of vines and trees the following is recommended:
II.—Caustic soda 5 pounds Rosin 40 pounds Water, a sufficient quantity.
Dissolve the soda in 4 gallons of water, by the aid of heat, add the rosin and after it is dissolved and while boiling add, slowly, enough water to make 50 gallons. For use, 1 part of this mixture is diluted with 10 parts of water and about 5 gallons of the product poured into a depression near the root of the vine or tree.
«For Cochineal Insects.»—An emulsion for fumagine (malady of orange trees caused by the cochineal insect) and other diseases caused by insects is as follows:
Dissolve, hot, 4 parts of black soap in 15 parts of hot water. Let cool to 104° F., and pour in 10 parts of ordinary petroleum, shaking vigorously. Thus an emulsion of _café au lait_ color is obtained, which may be preserved indefinitely. For employment, each part of the emulsion is diluted, according to circumstances, with from 10 to 20 parts of water.
«For Locusts.»—Much trouble is experienced in the Transvaal and Natal with locust pests, the remedies used being either a soap spray, containing 1 pound ordinary household soap in 5 gallons of water, or arsenite of soda, the latter being issued by the government for the purpose, and also used for the destruction of prickly pear, and as a basis of tick dips. A solution of 1 pound in 10 gallons of water is employed for full-grown insects, and of 1 pound in 20 gallons of water for newly hatched ones, 1 pound of sugar being added to each pound of arsenite dissolved. The solution sometimes causes sores on the skin, and the natives employed in its use are given grease to rub over themselves as a measure of protection. An advantage of the arsenite solution over soap is that much less liquid need be used.
A composition for the destruction of pear blight, which has been patented in {423} the United States, is as follows: Peppermint oil, 16 parts; ammonia water, 60 parts; calomel, 30 parts; and linseed oil, 1,000 parts.
«For Moths and Caterpillars.»—
I.—Venice turpentine 200 parts Rosin 1,000 parts Turpentine 140 parts Tar 80 parts Lard 500 parts Rape oil 240 parts Tallow 200 parts
II.—Rosin 50 parts Lard 40 parts Stearine oil 40 parts
«For Non-Masticating Insects.»—For protection against all non-masticating and many mandibulate insects, kerosene oil is much used. It is exhibited in the form of emulsion, which may be made as follows:
Kerosene 2 gallons Common soap 8 ounces Water 1 gallon
Dissolve the soap in the water by the aid of heat, bring to the boiling point, and add the kerosene in portions, agitating well after each addition. This is conveniently done by means of the pump to be used for spraying the mixture.
«For Scale Insects.»—For destroying scale insects dilute the cochineal emulsion (see above) with 9 times its volume of water; in the case of most others, except lice, dilute with 14 volumes, and for the latter with 20 to 25 volumes.
For the extermination of scale insects, resinous preparations are also employed, which kill by covering them with an impervious coating. Such a wash may be made as follows:
Rosin 3 1/2 pounds Caustic soda 1 pound Fish oil 8 ounces Water 20 gallons
Boil the rosin, soda, and oil with a small portion of the water, adding the remainder as solution is effected.
For the San José scale a stronger preparation is required, the proportion of water being decreased by half, but such a solution is applied only when the tree is dormant.
«Scale Insects on Orange Trees.»—Scale insect enemies of orange trees are directly controlled in two ways: (1) By spraying the infested trees with some liquid insecticide, and (2) by subjecting them to the fumes of hydrocyanic acid gas, commonly designated as “gassing.” The latter method is claimed to be the most effective means known of destroying scale insects. In practice the method consists in closing a tree at night with a tent and filling the latter with the poisonous fumes generated by treating refined potassium cyanide (98 per cent) with commercial sulphuric acid (66 per cent) and water. The treatment should continue from 30 to 40 minutes, the longer time being preferable. The work is done at night to avoid the scalding which follows day applications, at least in bright sunshine.
The oily washes are said to be the best for the use by the spraying method. “Kerosene emulsion” is a type of these washes. A formula published by the United States Department of Agriculture follows: Kerosene, 2 gallons; whale-oil soap, 1/2 pound; water, 1 gallon. The soap is dissolved in hot water, the kerosene added, and the whole thoroughly emulsified by means of a power pump until a rather heavy, creamy emulsion is produced. The quantity of soap may be increased if desired. The insecticide is applied by spraying the infected tree with an ordinary force pump with spraying nozzle.
«Coating Against the Plant Louse.»—(_a_)—Mix 75 parts of green soap, 50 parts of linseed oil, and 25 parts of carbolic acid. Afterwards mix the mass with 15,000 parts of water.
(_b_) Mix 4 parts of carbolic acid with 100 parts water glass.
«Louse Washes.»—
Unslaked lime 18 parts Sulphur 9 parts Salt 6.75 parts
Mix as follows: A fourth part of the lime is slaked and boiled for 2/3 of an hour with the sulphur in 22.6 parts of water. The remainder of the lime is then slaked and added with the salt to the hot mixture. The whole is burned for another half hour or an hour, and then diluted to 353 parts. The fluid is applied lukewarm when the plants are not in
## active growth.
«For Slugs on Roses.»—
Powdered pyrethrum 8 ounces Powdered colocynth 4 ounces Powdered hellebore 16 ounces
«Flea Powder.»—
Naphthalene 4 ounces Talcum 10 ounces Tobacco dust 2 ounces
{424}
«To Keep Flaxseed Free from Bugs.»—As a container use a tin can with a close-fitting top. At the bottom of the can place a small vial of chloroform with a loose-fitting cork stopper. Then pour the flaxseed, whole or ground, into the can, covering the vial. Enough of the chloroform will escape from the vial to kill such insects as infest the flaxseed.
«INSECT POWDERS.»
Pyrethrum, whale oil (in the form of soap), fish oil (in the form of soap), soft soap, paraffine, Prussic acid, Paris green, white lead, sulphur, carbon bisulphide, acorus calamus, camphor, Cayenne pepper, tobacco, snuff, asafetida, white hellebore, eucalyptol, quassia, borax, acetic ether are most important substances used as insecticides, alone, or in combination of two or more of them. The Prussic acid and Paris green are dangerous poisons and require to be used with extreme care:
Insect powder is used for all small insects and as a destroyer of roaches. The observations of some experimenters seem to show that the poisonous principle of these flowers is non-volatile, but the most favorable conditions under which to use them are in a room tightly closed and well warmed. There may be two poisonous principles, one of which is volatile. Disappointment sometimes arises in their use from getting powder either adulterated, or which has been exposed to the air and consequently lost some of its efficiency.
The dust resulting from the use of insect powder sometimes proves irritating to the mucous membranes of the one applying the powder. This is best avoided by the use of a spray atomizer.
Persistence in the use of any means is an important element in the work of destroying insects. A given poison may be employed and no visible result follow at first, when in reality many may have been destroyed, enough being left to deceive the observer as to numbers. They multiply very rapidly, too, it must be remembered, and vigorous work is required to combat this increase. Where they can easily migrate from one householder’s premises to those of another, as in city “flats,” it requires constant vigilance to keep them down, and entire extermination is scarcely to be expected.
The ordinary insect powder on the market is made from pyrethrum carneum, pyrethrum roseum, and pyrethrum cinerariæ-folium. The first two are generally ground together and are commercially called Persian insect powder; while the third is commonly called Dalmatian insect powder. These powders are sold in the stores under many names and in combination with other powders under proprietary names.
The powder is obtained by crushing the dried flowers of the pellitory (pyrethrum). The leaves, too, are often used. They are cultivated in the Caucasus, whence the specific name Caucasicum sometimes used. Pyrethrum belongs to the natural order compositæ, and is closely allied to the chrysanthemum. The active principle is not a volatile oil, as stated by some writers, but a rosin, which can be dissolved out from the dry flowers by means of ether. The leaves also contain this rosin but in smaller proportions than the flowers. Tincture of pyrethrum is made by infusing the dried flowers in five times their weight of rectified spirit of wine. Diluted with water it is used as a lotion.
Borax powder also makes a very good insectifuge. It appears to be
## particularly effective against the common or kitchen cockroach. Camphor
is sometimes used, and the powdered dried root of acorus calamus, the sweet flag. A mixture of white lead with four times its weight of chalk is also highly recommended. The fish-oil soaps used in a powdered form are made from various recipes; of which the following is a typical example:
Powdered rosin 2 pounds Caustic soda 8 ounces Fish or whale oil 4 ounces
Boil together in a gallon of water for at least an hour, replacing some of the water if required.
The following insect-powder formulas are perfectly safe to use. In each instance insect powder relates to either one of the pyrethrum plants powdered, or to a mixture:
I.—Insect powder 8 ounces av. Powdered borax 8 ounces av. Oil of pennyroyal 2 fluidrachms
II.—Insect powder 8 ounces av. Borax 8 ounces av. Sulphur 4 ounces av. Oil of eucalyptus 2 fluidrachms
This formula is especially good for cockroaches:
III.—Insect powder 14 ounces av. Quassia in fine powder 6 ounces av. White hellebore, powdered 2 ounces av.
{425}
«Beetle Powder.»—
Cocoa powder 4 ounces Starch 8 ounces Borax 37 ounces
Mix thoroughly.
«Remedies Against Mosquitoes.»—A remedy to keep off mosquitoes, etc., is composed as follows: Cinnamon oil, 1 part; patchouli oil, 1 part; sandal oil, 4 parts; alcohol, 400 parts. This has a pleasant odor.
Oil of pennyroyal is commonly used to keep mosquitoes away. Some form of petroleum rubbed on the skin is even more efficient, but unpleasant to use, and if left on long enough will burn the skin.
A 40 per cent solution of formaldehyde for mosquito bites gives remarkably quick and good results. It should be applied to the bites as soon as possible with the cork of the bottle, and allowed to dry on. Diluted ammonia is also used to rub on the bites.
«Roach Exterminators.»—Borax, starch, and cocoa are said to be the principal ingredients of some of the roach foods on the market. A formula for a poison of this class is as follows:
Borax 37 ounces Starch 9 ounces Cocoa 4 ounces
«Moth Exterminators.»—Cold storage is the most effective means of avoiding the ravages of moths. Where this is impracticable, as in bureau drawers, camphor balls may be scattered about with satisfactory result. The following is also effective:
Spanish pepper 100 parts Turpentine oil 50 parts Camphor 25 parts Clove oil 10 parts Alcohol, 96 per cent 900 parts
Cut the Spanish pepper into little bits, and pour over them the alcohol and oil of turpentine. Let stand 2 or 3 days, then decant, and press out. To the liquid thus obtained add the camphor and clove oil, let stand a few days, then filter and fill into suitable bottles. To use, imbibe bits of bibulous paper in the liquid and put them in the folds of clothing to be protected.
«Protecting Stuffed Furniture from Moths.»—The stuffing, no matter whether consisting of tow, hair, or fiber, as well as the covering, should be coated with a 10 per cent solution of sulphur in carbon sulphide. The carbon sulphide dissolves the sulphur so as to cause a very fine division and to penetrate the fibers completely.
«Powder to Keep Moths Away.»—
Cloves 2 ounces Cinnamon 2 ounces Mace 2 ounces Black pepper 2 ounces Orris root 2 ounces
Powder coarsely and mix well together.
«Book-Worms.»—When these insects infest books they are most difficult to deal with, as the ordinary destructive agents injuriously affect the paper of the book. The books should be well beaten and exposed to the sun, and a rag moistened with formalin passed through the binding and the covers where possible. In other cases the bottom edge of the binding should be moistened with formalin before putting on the shelves, so that formaldehyde vapor can be diffused.
INSECT POWDERS: See Insecticides.
«INSECT TRAP.»
Into a china wash-basin, half filled with water, pour a glass of beer; cover the basin with a newspaper, in the center of which a small round hole is cut. Place it so that the edges of the paper lie on the floor and the hole is over the center of the basin. At night beetles and other insects, attracted by the smell of beer, climb the paper and fall through the hole into the liquid.
INSTRUMENT ALLOYS: See Alloys.
INSTRUMENT CLEANING: See Cleaning Preparations and Methods.
INSTRUMENT LACQUER: See Lacquers.
«Insulation»
«ELECTRIC INSULATION:»
«Insulating Varnishes.»—For earth cables and exposed strong current wires:
I.—Melt 2 parts of asphalt together with 0.4 parts of sulphur, add 5 parts of linseed-oil varnish, linseed oil or cottonseed oil, keep at 320° F. for 6 hours; next pour in oil of turpentine as required.
II.—Maintain 3 parts of elaterite with 2 parts of linseed-oil varnish at 392° F. for 5 to 6 hours; next melt 3 parts of asphalt, pour both substances together, and again maintain the temperature of {426} 392° F. for 3 to 4 hours, and then add 1 part of linseed-oil varnish and oil of turpentine as required.
III.—Insulating Varnish for Dynamos and Conduits with Low Tension.—Shellac, 4 parts; sandarac, 2 parts; linoleic acid, 2 parts; alcohol, 15 parts.
IV.—An insulating material which contains no caoutchouc is made by dissolving natural or coal-tar asphalt in wood oil, adding sulphur and vulcanizing at 572° F. The mixture of asphalt and wood oil may also be vulcanized with chloride of sulphur by the ordinary process used for caoutchouc. Before vulcanizing, a solution of rubber scraps in naphthalene is sometimes added and the naphthalene expelled by a current of steam. Substitutes for hard rubber are made of natural or artificial asphalt combined with heavy oil of tar and talc or infusorial earth.
Most of the insulating materials advertised under alluring names consist of asphalt combined with rosin, tar, and an inert powder such as clay or asbestos. Some contain graphite, which is a good conductor and therefore a very undesirable ingredient in an insulator.
«INSULATION AGAINST HEAT.»
An asbestos jacket is the usual insulator for boilers, steampipes, etc. The thicker the covering around the steampipe, the more heat is retained. A chief requirement for such protective mass is that it contains air in fine channels, so that there is no connection with the closed-in air. Most substances suitable for insulating are such that they can only with difficulty be used for a protective mass. The most ordinary way is to mix infusorial earth, kieselguhr, slag-wool, hair, ground cork, etc., with loam or clay, so that this plastic mass may be applied moist on the pipes. In using such substances care should be taken carefully to clean and heat the surfaces to be covered. The mass for the first coating is made into a paste by gradual addition of water and put on thick with a brush. After drying each time a further coating is applied. This is repeated until the desired thickness is reached. The last layer put on is rubbed smooth with the flat hand. Finally, strips of linen are wound around, which is coated with tar or oil paint as a protection against outside injuries. Cork stones consist of crushed cork with a mineral binding agent, and are sold pressed into various shapes.
«Leather Waste Insulation.»—Portions of leather, such as the fibers of sole leather of any size and form, are first rendered soft. The surface is then carded or the surface fibers scratched or raised in such a manner that when several pieces are pressed together their surface fibers adhere, and a compact, durable piece of leather is produced. The carding can be done by an ordinary batting machine, the action of which is so regulated that not only are the pieces of leather softened, but the fibers on their surfaces raised. The structure of the separate pieces of leather remains essentially unaltered. The raised fibers give the appearance of a furry substance to the leather. The batted pieces of leather are well mixed with paste or some suitable gum, either in or outside of the machine, and are then put into specially shaped troughs, where they are pressed together into layers of the required size and thickness. The separate pieces of leather adhere and are matted together. An agglutinant, if accessible, will contribute materially to the strength and durability of the product. The layers are dried, rolled, and are then ready for use. The pieces need not be packed together promiscuously. If larger portions of waste can be secured, the separate pieces can be arranged one upon another in rows. The larger pieces can also be used for the top and bottom of a leather pad, the middle portion of which consists of smaller pieces.
«INSULATION AGAINST MOISTURE, WEATHER, ETC.»
Experiments have shown that with the aid of red lead a very serviceable, resistive, and weatherproof insulation material may be produced from inferior fibers, to take the place, in many cases, of gutta-percha and other substances employed for insulating purposes, and
## particularly to effect the permanent insulation of aerial conductors
exposed to the action of the weather. Hackethal used for the purpose any vegetable fiber which is wrapped around the conductors to be insulated. The fiber is then saturated with liquid red lead. The latter is accomplished in the proportion of 4 to 5 parts of red lead, by weight, to 1 part, by weight, of linseed oil, by the hot or cold process, by mere immersion or under pressure. All the three substances, fiber, oil, and red lead, possess in themselves a certain insulating capacity, but none of them is alone of utility for such purposes. Even the red lead mixed with linseed oil does not possess in the liquid state a high degree of insulating power. {427} Only when both substances, the ingredients of the linseed oil capable of absorbing oxygen and the lead oxide rich in oxygen, oxidize in the air, a new gummy product of great insulating capacity results.
INTENSIFIERS: See Photography.
«IODINE SOLVENT.»
Iodine is quickly dissolved in oils by first rubbing up the iodine with one-fourth of its weight of potassium iodide and a few drops of glycerine, then adding a little oil and rubbing up again. The addition of the resultant liquid to the rest of the oil and a sharp agitation finishes the process.
IODINE SOAP: See Soap.
«IODOFORM DEODORIZER.»
Rub the part with about a teaspoonful of wine vinegar, after a previous thorough washing with soap.
«Iron»
(See also Metals and Steel.)
«To Color Iron Blue.»—One hundred and forty parts of hyposulphite of soda are dissolved in 1,000 parts of water; 35 parts of acetate of lead are dissolved in 1,000 parts of water; the two solutions are mixed, boiled, and the iron is immersed therein. The metal takes a blue color, such as is obtained by heating.
«To Distinguish Iron from Steel.»—The piece of metal to be tested is washed and then plunged into a solution of bichromate of potash, with the addition of considerable sulphuric acid. In half a minute or a minute the metal can be taken out, washed, and wiped. Soft steels and cast iron assume under this treatment an ash-gray tint. Tempered steels become almost black, without any metallic reflection. Puddled and refined irons remain nearly white and always have metallic reflections on the part of their surface previously filed, the remainder of the surface presenting irregular blackish spots.
Another method is to apply a magnet. Steel responds much more quickly and actively to the magnetic influence than does iron.
«Powder for Hardening Iron and Steel.»—For wrought iron place in the charge 20 parts, by weight, of common salt; 2 parts, by weight, of potassium cyanide; 0.3 parts, by weight, of potassium bichromate; 0.15 parts, by weight, of broken glass; and 0.1 part, by weight, of potassium nitrate for case-hardening. For cooling and hardening cast iron: To 60 parts, by weight, of water add 2.5 parts, by weight, of vinegar; 3 parts, by weight, of common salt; and 0.25 parts, by weight, of hydrochloric acid.
«Preventing the Peeling of Coatings for Iron.»—To obviate the scaling of coatings on iron, if exposed to the attacks of the weather, it is advisable to wash the iron thoroughly and to paint it next with a layer of boiling linseed oil. If thus treated, the paint never cracks off. If the iron objects are small and can be heated, it is advantageous to heat them previously and to dip them into linseed oil. The boiling oil enters all the pores of the metal and drives out the moisture. The coating adheres so firmly that frost, rain, nor wind can injure it.
«To Soften Iron Castings.»—To soften hard iron castings, heat the object to a high temperature, cover it over with fine coal dust or some similar substance, and allow it to cool gradually. When the articles are of small size, a number of them are packed in a crucible with substances yielding carbon to iron at a glowing heat. The crucible is then tightly closed, and placed in a stove or on an open fire. It is gradually heated and kept at a red heat for several hours, and then allowed to cool slowly. Cast-iron turnings, carbonate of soda, and unrefined sugar are recommended as substances suitable for packing in the crucible with the castings. If unrefined sugar alone is added, the quantity must not be too small. By this process the iron may be rendered extremely soft.
«To Whiten Iron.»—Mix ammoniacal salt in powder with an equal volume of mercury. This is dissolved in cold water and mixed thoroughly. Immerse the metal, heated to redness, in this bath and it will come out possessing the whiteness and beauty of silver. Care should be taken not to overheat the article and thus burn it.
IRON, BITING OFF RED HOT: See Pyrotechnics.
IRON, CEMENTS FOR: See Adhesives.
IRON, TO CLEAN: See Cleaning Preparations and Methods.
IRON TO CLOTH, GLUING: See Adhesives. {428}
IRON, HOW TO ATTACH RUBBER TO: See Adhesives, under Rubber Cements.
IRON OXALATE DEVELOPER: See Photography.
IRON SOLDERS: See Solders.
IRONING WAX: See Laundry Preparations.
IRON VARNISHES: See Varnishes.
ITCH, BARBERS’: See Ointments.
«Ivory»
(See also Bones, Shell, and Horn.)
«TO COLOR IVORY:»
Red.—The article is placed for 24 hours in water, 1,000 parts of which carry 100 parts of vinegar (acetic acid, 6 per cent), and from 1 to 5 parts of aniline red. As soon as it acquires the desired color pour off the liquid, let the ivory dry, and polish with Vienna lime.
Black.—Wash the article first in potash or soda lye and then put into a neutral solution of silver nitrate. Drain off the liquid and lay in the direct sunshine.
Red-Purple.—Put the article in a weak solution of triple gold chloride and then into direct sunshine.
Red.—For a different shade of red (from the first given), place the article for a short time in water weakly acidified with nitric acid and then in a solution of cochineal in ammonia.
Yellow.—Leave for several hours in a solution of lead acetate, rinse and dry. When quite dry place in a solution of potassium chromate.
To Color Billiard Balls Red.—
_Fiery Red._—Wash the article first in a solution of carbonate of soda, then plunge for a few seconds in a bath of equal parts of water and nitric acid. Remove, rinse in running water; then put in an alcoholic solution of fuchsine and let it remain until it is the required color.
_Cherry Red._—Clean by washing in the sodium carbonate solution, rinse and lay in a 2 per cent solution of tin chloride, for a few moments, then boil in a solution of logwood. Finally lay in a solution of potassium carbonate until it assumes the desired color.
_Pale Red._—Wash in soda solution, rinse and lay for 25 minutes in a 5 per cent solution of nitric acid, rinse, then lay for several minutes in a weak solution of tin chloride. Finally boil in the following solution: Carmine, 2 parts; sodium carbonate, 12 parts; water, 200 parts; acetic acid enough to saturate.
_Brown._—Apply several coats of an ammoniacal solution of potassium permanganate. Similar results are obtained if the solution is diluted with vinegar, and the ivory article allowed to remain in the liquid for some time.
«Etching on Ivory» (see also Etching).—Although decorations on ivory articles, such as umbrella handles, cuff-buttons, fans, book-covers, boxes, etc., are generally engraved, the work is frequently done by etching. The patterns must be very delicate, and are executed in lines only. The simplest way is to cover the surface with a thin rosin varnish. Then transfer the pattern and scratch it out accurately with a pointed needle. Otherwise proceed same as in etching on metal and stone, making an edge of modeling wax around the surface to be etched and pouring on the acid, which consists, in this case, of sulphuric acid, 1 part, to which 5 to 6 parts of water are added. It acts very quickly. The lines turn a deep black. If brown lines are desired, dissolve 1 part of silver nitrate in 5 parts of water, etch for a short time, and expose the article for a few hours to the light, until the design turns brown. Very often etchings in ivory are gilded. For this purpose, fill the etched patterns accurately with siccatives, using a writing pen, dry, and dab on gold leaf. After a few hours remove the superfluous gold with wadding, and the design will be nicely gilded. Etched ivory articles present a very handsome appearance if they are first covered with a silvery gloss, the design being gilded afterwards. For the former purpose the etched object is laid in the above described solution of silver nitrate until it has acquired a dark yellow color. Then rinse it off in clean water and, while still moist, expose to direct sunlight. After 3 to 4 hours the surface becomes entirely black, but will take on a fine silvery luster if rubbed with soft leather.
«Flexible Ivory.»—To soften ivory and render it flexible put pure phosphoric acid (specific gravity, 1.13) into a wide-mouthed bottle or jar that can be covered, and steep the ivory in this until it partially loses its opacity; then wash the ivory in cold, soft water and dry, when the ivory will be found soft and flexible. {429} It regains its hardness in course of time when freely exposed to air, although its flexibility can be restored by immersing the ivory in hot water.
Another softening fluid is prepared by mixing 1 ounce of spirit of niter with 5 ounces of water and steeping the ivory in the fluid for 4 or 5 days.
«Hardened Ivory.»—To restore the hardness to ivory that has been softened by the above methods, wrap it in a sheet of white writing paper, cover it with dry decrepitated salt, and let it remain thus covered for 24 hours. The decrepitated salt is prepared by strewing common kitchen salt on a plate or dish and standing same before a fierce fire, when the salt loses its crystalline appearance and assumes a dense opaque whiteness.
«IMITATION IVORY:»
See also Casein and Plaster.
Manufacture of Compounds Imitating Ivory, Shell, etc.—Casein, as known, may act the part of an acid and combine with bases to form caseinates or caseates; among these compounds, caseinates of potash, of soda, and of ammonia are the only ones soluble in water; all the others are insoluble and may be readily prepared by double decomposition. Thus, for example, to obtain caseinate of alumina, it is sufficient to add to a solution of casein in caustic soda a solution of sulphate of alumina; an insoluble precipitate of casein, or caseinate of alumina, is instantly formed. This precipitate ought to be freed from the sulphate of soda (formed by double decomposition) by means of prolonged washing.
When pure, ordinary cellulose may be incorporated with it by this process, producing a new compound, cheaper than pure cellulose, although possessing the same properties, and capable of replacing it in all its applications. According to the results desired, in transparency, color, hardness, etc., the most suitable caseinate should be selected. Thus, if a translucent compound is to be obtained, the caseinate of alumina yields the best. If a white compound is desired, the caseinate of zinc or of magnesia should be chosen; and for colored products the caseinates of iron, copper, and nickel will give varied tints.
The process employed for the new products, with a base of celluloid and caseinate, is as follows: On one hand casein is dissolved in a solution of caustic soda (100 of water for 10 to 25 of soda), and this liquid is filtered, to separate the matters not dissolved and the impurities.
On the other hand, a salt (of the base of which the caseinate is desired) is dissolved, and the solution filtered. It is well not to operate on too concentrated a solution. The two solutions are mixed in a reservoir furnished with a mechanical stirrer, in order to obtain the insoluble caseinate precipitate in as finely divided a state as possible. This precipitate should be washed thoroughly so as to free it from the soda salt formed by double decomposition, but on account of its gummy or pasty state, this washing presents certain difficulties, and should be done carefully. After the washing it should be freed from the greater part of water contained by draining, followed by drying, or energetic pressing; then it is washed in alcohol, dried or pressed again, and is ready to be incorporated in the mass of the celluloid.
For the latter immersion and washing, it has been found that an addition of 1 to 5 per cent of borax is advantageous, for it renders the mass more plastic, and facilitates the operation of mixing. This may be conducted in a mixing apparatus; but, in practice, it is found preferable to effect it with a rolling mill, operated as follows:
The nitro-cellulose is introduced in the plastic state, and moistened with a solution of camphor in alcohol (40 to 50 parts of camphor in 50 to 70 parts of alcohol for 100 parts of nitro-cellulose) as it is practiced in celluloid factories.
This plastic mass of nitro-cellulose is placed in a rolling mill, the cylinders of which are slightly heated at the same time as the caseinate, prepared as above; then the whole mass is worked by the cylinders until the mixture of the two is perfectly homogeneous, and the final mass is sufficiently hard to be drawn out in leaves in the same way as practiced for pure celluloid. These leaves are placed in hydraulic presses, where they are compressed, first hot, then cold, and the block thus formed is afterwards cut into leaves of the thickness desired. These leaves are dried in an apparatus in the same way as ordinary celluloid. The product resembles celluloid, and has all its properties. At 195° to 215° F. it becomes quite plastic, and is easily molded. It may be sawed, filed, turned, and carved without difficulty, and takes on a superb polish. It burns less readily than celluloid, and its combustibility diminishes in proportion as the percentage of caseinate increases; finally, the cost price is less than that of celluloid, {430} and by using a large proportion of caseinate, products may be manufactured at an extremely low cost.
«IVORY AND BONE BLEACHES.»
If simply dirty, scrub with soap and tepid water, using an old tooth or nail brush for the purpose. Grease stains may be sometimes removed by applying a paste of chalk or whiting and benzol, covering the article so that the benzol may not dry too rapidly. Carbon disulphide (the purified article) may be used in place of benzol. When dry, rub off with a stiff brush. If not removed with the first application, repeat the process. Delicately carved articles that show a tendency to brittleness should be soaked for a short time in dilute phosphoric acid before any attempt to clean them is made. This renders the minuter portions almost ductile, and prevents their breaking under cleaning.
The large scratched brush should be treated as follows: If the scratches are deep, the surface may be carefully rubbed down to the depth of the scratch, using the finest emery cloth, until the depth is nearly reached, then substituting crocus cloth.
To restore the polish nothing is superior to the genuine German putz pomade, following by rubbing first with chamois and finishing off with soft old silk. The more “elbow grease” put into the rubbing the easier the task, as the heat generated by friction seems to lend a sort of ductility to the surface. To remove the yellow hue due to age, proceed as follows: Make a little tripod with wire, to hold the object a few inches above a little vessel containing lime chloride moistened with hydrochloric acid; put the object on the stand, cover the whole with a bell glass, and expose to direct sunlight. When bleached, remove and wash in a solution of sodium bicarbonate, rinse in clear water and dry.
Like mother-of-pearl, ivory is readily cleaned by dipping in a bath of oxygenized water or immersing for 15 minutes in spirits of turpentine, and subsequently exposing to the sun for 3 or 4 days. For a simple cleaning of smooth articles, wash them in hot water, in which there has been previously dissolved 100 parts (by weight) of bicarbonate of soda per 1,000 parts of water. To clean carved ivory make a paste of very fine, damp sawdust, and put on this the juice of 1 or 2 lemons, according to the article to be treated. Now apply a layer of this sawdust on the ivory, and when dry brush it off and rub the object with a chamois.
«IVORY TESTS.»
Many years ago an article was introduced in the industrial world which in contradistinction to the genuine animal ivory, has its origin in the vegetable kingdom, being derived from the nut of a palm-like shrub called phytelephasmacrocarpa, whose fruit reaches the size of an apple. This fruit has a very white, exceedingly hard kernel which can be worked like ivory. A hundred of these fruits only costing about $1, their use offers great advantages. Worked on the lathe this ivory can be passed off as the genuine article, it being so much like it that it is often sold at the same price. It can also be colored just like genuine ivory.
To distinguish the two varieties of ivory, the following method may be employed: Concentrated sulphuric acid applied to vegetable ivory will cause a pink coloring in about 10 or 12 minutes, which can be removed again by washing with water. Applied on genuine ivory, this acid does not affect it in any manner.
IVORY BLACK: See Bone Black.
IVORY CEMENT: See Adhesives.
IVORY GILDING: See Plating.
IVORY POLISHES: See Polishes.
JAPAN BLACK: See Paints.
JAPANNING AND JAPAN TINNING: See Varnishes.
JASMINE MILK: See Cosmetics.
JELLY (FRUIT) EXTRACT: See Essences and Extracts.
JEWELERS’ CEMENTS: See Adhesives.
JEWELERS’ CLEANING PROCESSES: See Cleaning Preparations and Methods.
«Jewelers’ Formulas»
(See also Gems, Gold, and Watchmakers’ Recipes.)
«Coloring Gold Jewelry.»—Following are several recipes for coloring: Saltpeter, 40 parts; alum, 30 parts; sea salt, 30 parts; or, liquid ammonia, 100 parts; sea salt, 3 parts; water, 100 parts. Heat without allowing to boil and plunge {431} the objects into it for 2 or 3 minutes, stirring constantly; rinse in alum water and then in clean water. Another recipe: Calcium bromide, 100 parts; bromine, 5 parts. Place the articles in this solution, with stirring, for 2 to 3 minutes; next wash in a solution of hyposulphite of sodium and rinse in clean water. Another: Verdigris, 30 parts; sea salt, 30 parts; blood stone, 30 parts; sal ammoniac, 30 parts; alum, 5 parts. Grind all and stir with strong vinegar; or, verdigris, 100 parts; hydrochlorate of ammonia, 100 parts; saltpeter, 65 parts; copper filings, 40 parts. Bray all and mix with strong vinegar.
«To Widen a Jewel Hole.»—Chuck the hole in a lathe with cement. Place a spirit lamp underneath to prevent the cement from hardening. Hold the pointed bit against the hole, while the lathe is running, until the hole is true, when the lamp should be removed. The broach to widen the hole should be made of copper, of the required size and shape, and the point, after being oiled, should be rolled in diamond dust until it is entirely covered. The diamond dust should then be beaten in with a burnisher, using very light blows so as not to bruise the broach. After the hole is widened as desired, it requires polishing with a broach made of ivory and used with oil and the finest diamond dust, loose, not driven into the broach.
«To Clean Jet Jewelry.»—Reduce bread crumbs into small particles, and introduce into all the curves and hollows of the jewelry, while rubbing with a flannel.
«Coloring Common Gold.»—In coloring gold below 18 carat, the following mixture may be used with success, and if carefully employed, even 12 carat gold may be colored by it: Take nitrate of potassa (saltpeter), 4 parts, by weight; alum, 2 parts; and common salt, 2 parts. Add sufficient warm water to mix the ingredients into a thin paste; place the mixture in a small pipkin or crucible and allow to boil. The article to be colored should be suspended by a wire and dipped into the mixture, where it should remain from 10 to 20 minutes. The article should then be removed and well rinsed in hot water, when it must be scratch brushed, again rinsed and returned to the coloring salts for a few minutes; it is then to be again rinsed in hot water, scratch brushed, and finally brushed with soap and hot water, rinsed in hot water, and placed in boxwood sawdust. The object being merely to remove the alloy, as soon as the article has acquired the proper color of fine gold it may be considered sufficiently acted upon by the above mixture. The coloring salts should not be used for gold of a lower standard than 12 carat, and, even for this quality of gold, some care must be taken when the articles are of a very slight make.
«Shades of Red, etc., on Matt Gold Bijouterie.»—For the production of the red and other shades on matt gold articles, the so-called gold varnishes are employed, which consist of shellac dissolved in alcohol and are colored with gum rosins. Thus a handsome golden yellow is obtained from shellac, 35 parts; seed-lac, 35 parts; dragon’s blood, 50 parts; gamboge, 50 parts; dissolved in 400 parts of alcohol; the clear solution is decanted and mixed with 75 parts of Venice turpentine. By changing the amounts of the coloring rosins, shades from bright gold yellow to copper color are obtained. The varnish is applied evenly and after drying is wiped off from the raised portions of the article by means of a pad of wadding dipped into alcohol, whereby a handsome patination effect is produced, since the lacquer remains in the cavities. Chased articles are simply rubbed with earth colors ground into a paste with turpentine oil, for which purpose burnt sienna, fine ochers of a golden color, golden yellow, and various shades of green are employed.
I.—Yellow wax 32 parts Red bole 3 parts Crystallized verdigris 2 parts Alum 2 parts
II.—Yellow wax 95 parts Red bole 64 parts Colcothar 2 parts Crystallized verdigris 32 parts Copper ashes 20 parts Zinc vitriol 32 parts Green vitriol 16 parts Borax 1 part
The wax is melted and the finely powdered chemicals are stirred in, in rotation. If the gilt bronze goods are to obtain a lustrous orange shade, apply a mixture of ferric oxide, alum, cooking salt, and vinegar in the heated articles by means of a brush, heating to about 266° F. until the shade commences to turn black and water sprinkled on will evaporate with a hissing sound, then cool in water, dip in a mixture of 1 part of nitric acid with 40 parts of water, rinse {432} thoroughly, dry, and polish. For the production of a pale-gold shade use a wax preparation consisting of:
III.—Yellow wax 19 parts Zinc vitriol 10 parts Burnt borax 3 parts
Green-gold color is produced by a mixture of:
IV.—Saltpeter 6 parts Green vitriol 2 parts Zinc vitriol 1 part Alum 1 part
«To Matt Gilt Articles.»—If it is desired to matt gilt articles partly or entirely, the portions which are to remain burnished are covered with a mixture of chalk, sugar, and mucilage, heating until this “stopping-off” covering shows a black color. On the places not covered apply a matting powder consisting of:
Saltpeter 40 parts Alum 25 parts Cooking salt 35 parts
Heat the objects to about 608° F., whereby the powder is melted and acquires the consistency of a thin paste. In case of too high a temperature decomposition will set in.
«To Find the Number of Carats.»—To find the number of carats of gold in an object, first weigh the gold and mix with seven times its weight in silver. This alloy is beaten into thin leaves, and nitric acid is added; this dissolves the silver and copper. The remainder (gold) is then fused and weighed; by comparing the first and last weights the number of carats of pure gold is found. To check repeat several times.
«Acid Test for Gold.»—The ordinary ready method of ascertaining whether a piece of jewelry is made of gold consists in touching it with a glass stopper wetted with nitric acid, which leaves gold untouched, but colors base alloys blue from the formation of nitrate of copper.
«Imitation Diamonds.»—I.—Minium, 75 parts (by weight); washed white sand, 50 parts; calcined potash, 18 parts; calcined borax, 6 parts; bioxide of arsenic, 1 part. The sand must be washed in hydrochloric acid and then several times in clean water. The specific gravity of this crystal glass is almost the same as that of the diamond.
II.—Washed white sand, 100 parts (by weight): minium, 35 parts; calcined potash, 25 parts; calcined borax, 20 parts; nitrate of potash (crystals), 10 parts; peroxide of manganese, 5 parts. The sand must be washed as above stated.
«Diamantine.»—This substance consists of crystallized boron, the basis of borax. By melting 100 parts of boracic acid and 80 parts of aluminum crystals is obtained the so-called bort, which even attacks diamond. The diamantine of commerce is not so hard.
«To Refine Board Sweepings.»—The residue resulting from a jobbing jeweler’s business, such as board sweepings and other residuum, which is continually accumulating and which invariably consists of all mixed qualities of standard, may have the precious metals recovered therefrom in a very simple manner, as follows: Collect the residue and burn it in an iron ladle or pan, until all grease or other organic matter is destroyed. When cool mix with 1/5 part soda-ash, and melt in a clay crucible. When the metal is thoroughly melted it will leave the flux and sink to the bottom of the crucible; at this stage the flux assumes the appearance of a thin fluid, and then is the time to withdraw the pot from the fire. The metal in the crucible—but not the flux—may now be poured into a vessel of water, stirring the water in a circular direction while the metal is being poured in, which causes it to form into small grains, and so prepares it for the next process. Dissolve the grains in a mixture of nitric acid and water in equal quantities. It takes about four times the quantity of liquid as metal to dissolve. The gold remains undissolved in this mixture, and may be recovered by filtering or decanting the liquid above it in the dissolving vessel; it is then dried, mixed with a little flux, and melted in the usual manner, whereupon pure gold will be obtained. To recover the silver, dilute the solution which has been withdrawn from the gold with six times its bulk of water, and add by degrees small quantities of finely powdered common salt, and this will throw down the silver into a white, curdy powder of chloride of silver. Continue to add salt until no cloudiness is observed in the solution, when the water above the sediment may be poured off; the sediment is next well washed with warm water several times, then dried and melted in the same manner as the gold, and you will have a lump of pure silver.
«Restoration of the Color of Turquoises.»—After a certain time turquoises lose a part of their fine color. It is easy to restore the color by immersing them in a solution of carbonate of soda. But it seems that the blue cannot be restored anew after this operation, if it again becomes dull. The above applies to {433} common turquoises, and not to those of the Orient, of which the color does not change.
«Colorings for Jewelers’ Work.»—I.—Take 40 parts of saltpeter; 30 parts of alum; 30 parts of sea salt; or 100 grams of liquid ammonia; 3 parts sea salt; and 100 parts water. This is heated without bringing it to a boil, and the articles dipped into it for from 2 to 3 minutes, stirring the liquid constantly; after this bath they are dipped in alum water and then thoroughly rinsed in clean water.
II.—One hundred parts of calcium bromide and 2 parts of bromium. The objects are allowed to remain in this solution (which must be also constantly stirred) for from 2 to 3 minutes, then washed in a solution of sodium hyposulphite, after which they must be rinsed in clean water.
III.—Thirty parts of verdigris; 30 parts of sea salt; 30 parts of hematite; 30 parts of sal ammoniac, and 5 parts of alum. This must be all ground up together and mixed with strong vinegar; or we may also use 100 parts of verdigris; 100 parts of hydrochlorate of ammonia; 65 parts of saltpeter, and 40 parts of copper filings, all of which are to be well mixed with strong vinegar.
«22-Carat Solder.»—Soldering is a process which, by means of a more fusible compound, the connecting surfaces of metals are firmly secured to each other, but, for many practical purposes, it is advisable to have the fusing point of the metal and solder as near each other as possible, which, in the majority of cases, preserves a union more lasting, and the joint less distinguishable, in consequence of the similarity of the metal and solder in color, which age does not destroy, and this is not the case with solders the fusible points of which are very low. The metal to be soldered together must have an affinity for the solder, otherwise the union will be imperfect; and the solder should likewise act upon the metal, partly by this affinity or chemical attraction, and partly by cohesive force, to unite the connections soundly and firmly together. Solders should therefore be prepared suitable to the work in hand, if a good and lasting job is to be made. It should always be borne in mind that the higher the fusing point of the gold alloy—and this can be made to vary considerably, even with any specified quality—the harder solder must be used, for, in the case of a more fusible mixture of gold, the latter would melt before the solder and cause the work to be destroyed. A very good formula for the first, or ordinary, 22-carat alloy is this:
dwts. grs. Fine gold 1 0 Fine silver 0 3 Fine copper 0 2 ──────── 1 5
This mixture will answer all the many purposes of the jobber; for soldering high quality gold wares that come for repairs, particularly wedding rings, it will be found admirably suited. If an easier solder is wanted, and such is very often the case with jobbing jewelers, especially where several solderings have to be accomplished, it is as well to have at hand a solder which will not disturb the previous soldering places, for if this is not prevented a very simple job is made very difficult, and a lot of time and patience wholly wasted. To guard against a thing of this kind the following solder may be employed on the top of the previous one:
dwts. grs. Fine gold 1 0 Fine silver 0 3 Yellow brass 0 2 ──────── 1 5
This solder is of the same value as the previous one, but its melting point is lower, and it will be found useful for many purposes that can be turned to good account in a jobbing jeweler’s business.
«JEWELERS’ ALLOYS:»
See also Alloys and Solders.
«18-Carat Gold for Rings.»—Gold coin, 19 1/2 grains; pure copper, 3 grains; pure silver, 1 1/2 grains.
«Cheap Gold, 12 Carat.»—Gold coin, 25 grains; pure copper, 13 1/2 grains; pure silver, 7 1/3 grains.
«Very Cheap 4-Carat Gold.»—Copper, 18 parts; gold, 4 parts; silver, 2 parts.
«Imitations of Gold.»—I.—Platina, 4 pennyweights; pure copper, 2 1/4 pennyweights; sheet zinc, 1 pennyweight; block tin, 1 3/4 pennyweights; pure lead, 1 1/2 pennyweight. If this should be found too hard or brittle for practical use, remelting the composition with a little sal ammoniac will generally render it malleable as desired.
II.—Platina, 2 parts; silver, 1 part; copper, 3 parts. These compositions, when properly prepared, so nearly resemble pure gold that it is very difficult to {434} distinguish them therefrom. A little powdered charcoal, mixed with metals while melting, will be found of service.
«Best Oreide of Gold.»—Pure copper, 4 ounces; sheet zinc, 1 3/4 ounces; magnesia, 5/8 ounce; sal ammoniac, 11/32 ounce; quicklime, 9/32 ounce; cream tartar, 7/8 ounce. First melt the copper at as low a temperature as it will melt; then add the zinc, and afterwards the other articles in powder, in the order named. Use a charcoal fire to melt these metals.
«Bushing Alloy for Pivot Holes, etc.»—Gold coin, 3 pennyweights; silver, 1 pennyweight, 20 grains; copper, 3 pennyweights, 20 grains; palladium, 1 pennyweight. The best composition known for the purpose named.
«Gold Solder for 14- to 16-Carat Work.»—Gold coin, 1 pennyweight; pure silver, 9 grains; pure copper, 6 grains; brass, 3 grains.
«Darker Solder.»—Gold coin, 1 pennyweight; pure copper, 8 grains; pure silver, 5 grains; brass, 2 grains. Melt together in charcoal fire.
«Solder for Gold.»—Gold, 6 pennyweights; silver, 1 pennyweight; copper, 2 pennyweights.
«Soft Gold Solder.»—Gold, 4 parts; silver, 1 part; copper, 1 part.
«Solders for Silver» (for the use of jewelers).—Fine silver, 19 pennyweights; copper, 1 pennyweight; sheet brass, 10 pennyweights.
«White Solder for Silver.»—Silver, 1 ounce; tin, 1 ounce.
«Silver Solder for Plated Metal.»—Fine silver, 1 ounce; brass, 10 pennyweights.
«Solders for Gold.»—I.—Silver, 7 parts; copper, 1 part; with borax.
II.—Gold, 2 parts; silver, 1 part; copper, 1 part.
III.—Gold, 3 parts; silver, 3 parts; copper, 1 part; zinc, 1/2 part.
«For Silver.»—Silver, 2 parts; brass, 1 part; with borax; or, silver, 4 parts; brass, 3 parts; zinc, 1/18 part; with borax.
«Gold Solders» (see also Solders).—I.—Copper, 24.24 parts; silver, 27.57 parts; gold, 48.19 parts.
II.—Enamel Solder.—Copper, 25 parts; silver, 7.07 parts; gold, 67.93 parts.
III.—Copper, 26.55 parts; zinc, 6.25 parts; silver, 31.25 parts; gold, 36 parts.
IV.—Enamel Solder.—Silver, 19.57 parts; gold, 80.43 parts.
«Solder for 22-Carat Gold.»—Gold of 22 carats, 1 pennyweight; silver, 2 grains; copper, 1 grain.
«For 18-Carat Gold.»—Gold of 18 carats, 1 pennyweight; silver, 2 grains; copper, 1 grain.
«For Cheaper Gold.»—I.—Gold, 1 pennyweight; silver, 10 grains; copper, 8 grains.
II.—Fine gold, 1 pennyweight; silver, 1 pennyweight; copper, 1 pennyweight.
«Silver Solders» (see also Solders).—I. (Hard.)—Copper, 30 parts; zinc, 12.85 parts; silver, 57.15 parts.
II.—Copper, 23.33 parts; zinc, 10 parts; silver, 66.67 parts.
III.—Copper, 26.66 parts; zinc, 10 parts; silver, 63.34 parts.
IV. (Soft.)—Copper, 14.75 parts; zinc, 8.50 parts; silver, 77.05 parts.
V.—Copper, 22.34 parts; zinc, 10.48 parts; silver, 67.18 parts.
VI.—Tin, 63 parts; lead, 37 parts.
«FOR SILVERSMITHS:»
I.—Sterling Silver.—Fine silver, 11 ounces, 2 pennyweights; fine copper, 18 pennyweights.
II.—Equal to Sterling.—Fine silver, 1 ounce; fine copper, 1 pennyweight, 12 grains.
III.—Fine silver, 1 ounce; fine copper, 5 pennyweights.
IV.—Common Silver for Chains.—Fine silver, 6 pennyweights; fine copper, 4 pennyweights.
V.—Solder.—Fine silver, 16 pennyweights; fine copper, 12 grains; pin brass, 3 pennyweights, 12 grains.
VI.—Alloy for Plating.—Fine silver, 1 ounce; fine copper, 10 pennyweights.
VII.—Silver Solder.—Fine silver, 1 ounce; pin brass, 10 pennyweights; pure spelter, 2 pennyweights.
VIII.—Copper Solder for Plating.—Fine silver, 10 pennyweights; fine copper, 10 pennyweights.
IX.—Common Silver Solder.—Fine silver, 10 ounces; pin brass, 6 ounces, 12 pennyweights; spelter, 12 pennyweights.
X.—Silver Solder for Enameling.—Fine silver, 14 pennyweights; fine copper, 8 pennyweights.
XI.—For Filling Signet Rings.—Fine silver, 10 ounces; fine copper, 1 ounce, 16 pennyweights; fine pin brass, 6 ounces, 12 pennyweights; spelter, 12 pennyweights. {435}
XII.—Silver Solder for Gold Plating.—Fine silver, 1 ounce; fine copper, 5 pennyweights; pin brass, 5 pennyweights.
XIII.—Mercury Solder.—Fine silver, 1 ounce; pin brass, 10 pennyweights; bar tin, 2 pennyweights.
XIV.—Imitation Silver.—Fine silver, 1 ounce; nickel, 1 ounce, 11 grains; fine copper, 2 ounces, 9 grains.
XV.—Fine silver, 3 ounces; nickel, 1 ounce, 11 pennyweights; fine copper, 2 ounces, 9 grains; spelter, 10 pennyweights.
XVI.—Fine Silver Solder for Filigree Work.—Fine silver, 4 pennyweights, 6 grains; pin brass, 1 pennyweight.
Bismuth Solder.—Bismuth, 3 ounces; lead, 3 ounces, 18 pennyweights; tin, 5 ounces, 6 pennyweights.
«BRASS:»
I.—Yellow Brass for Turning.—(Common article.)—Copper, 20 pounds; zinc, 10 pounds; lead, 4 ounces.
II.—Copper, 32 pounds; zinc, 10 pounds; lead, 1 pound.
III.—Red Brass Free, for Turning.—Copper, 100 pounds; zinc, 50 pounds; lead, 10 pounds; antimony, 44 ounces.
IV.—Best Red Brass for Fine Castings.—Copper, 24 pounds; zinc, 5 pounds; bismuth, 1 ounce.
V.—Red Tombac.—Copper, 10 pounds; zinc, 1 pound.
VI.—Tombac.—Copper, 16 pounds; tin, 1 pound; zinc, 1 pound.
VII.—Brass for Heavy Castings.—Copper, 6 to 7 parts; tin, 1 part; zinc, 1 part.
VIII.—Malleable Brass.—Copper, 70.10 parts; zinc, 29.90 parts.
IX.—Superior Malleable Brass.—Copper, 60 parts; zinc, 40 parts.
X.—Brass.—Copper, 73 parts; zinc, 27 parts.
XI.—Copper, 65 parts; zinc, 35 parts.
XII.—Copper, 70 parts; zinc, 30 parts.
XIII.—German Brass.—Copper, 1 pound; zinc, 1 pound.
XIV.—Watchmakers’ Brass.—Copper, 1 part; zinc, 2 parts.
XV.—Brass for Wire.—Copper, 34 parts; calamine, 56 parts.
XVI.—Brass for Tubes.—Copper, 2 parts; zinc, 1 part.
XVII.—Brass for Heavy Work.—Copper, 100 parts; tin, 15 parts; zinc, 15 parts.
XVIII.—Copper, 112 parts; tin, 13 parts; zinc, 1 part.
XIX.—Tombac or Red Brass.—Copper, 8 parts; zinc, 1 part.
XX.—Brass.—Copper, 3 parts; melt, then add zinc, 1 part.
XXI.—Buttonmakers’ Fine Brass.—Brass, 8 parts; zinc, 5 parts.
XXII.—Buttonmakers’ Common Brass.—Button brass, 6 parts; tin, 1 part; lead, 1 part. Mix.
XXIII.—Mallet’s Brass.—Copper, 25.4 parts; zinc, 74.6 parts. Used to preserve iron from oxidizing.
XXIV.—Best Brass for Clocks.—Rose copper, 85 parts; zinc, 14 parts; lead, 1 part.
«GOLD ALLOYS:»
See also Gold Alloys, under Alloys.
Gold of 22 carats fine being so little used is intentionally omitted.
I.—Gold of 18 Carats, Yellow Tint.—Gold, 15 pennyweights; silver, 2 pennyweights, 18 grains; copper, 2 pennyweights, 6 grains.
II.—Gold of 18 Carats, Red Tint.—Gold, 15 pennyweights; silver, 1 pennyweight, 18 grains; copper, 3 pennyweights, 6 grains.
III.—Spring Gold of 16 Carats.—Gold, 1 ounce, 16 pennyweights; silver, 6 pennyweights; copper, 12 pennyweights. This when drawn or rolled very hard makes springs little inferior to steel.
IV.—Jewelers’ Fine Gold, Yellow Tint, 16 Carats Nearly.—Gold, 1 ounce; silver, 7 pennyweights; copper, 5 pennyweights.
V.—Gold of Red Tint, 16 Carats.—Gold, 1 ounce; silver, 2 pennyweights; copper, 8 pennyweights.
Sterling Gold Alloys.—I.—Fine gold, 18 pennyweights, 12 grains; fine silver, 1 pennyweight; fine copper, 12 grains.
II.—Dry Colored Gold Alloys, 17 Carat.—Fine gold, 15 pennyweights; fine silver, 1 pennyweight, 10 grains; fine copper, 4 pennyweights, 17 grains.
III.—18 Carat.—Fine gold, 1 ounce; fine silver, 4 pennyweights, 10 grains; fine copper, 2 pennyweights, 5 grains.
IV.—18 Carat.—Fine gold, 15 pennyweights; fine silver, 2 pennyweights, 4 grains; fine copper, 2 pennyweights, 19 grains.
V.—18 Carat.—Fine gold, 18 pennyweights; fine silver, 2 pennyweights, 18 {436} grains; fine copper, 3 pennyweights, 18 grains.
VI.—19 Carat.—Fine gold, 1 ounce; fine silver, 2 pennyweights, 6 grains; fine copper, 3 pennyweights, 12 grains.
VII.—20 Carat.—Fine gold, 1 ounce; fine silver, 2 pennyweights; fine copper, 2 pennyweights, 4 grains.
VIII.—22 Carat.—Fine gold, 18 pennyweights; fine silver, 12 grains; fine copper, 1 pennyweight, 3 grains.
IX.—Gold Solder for the Foregoing Alloys.—Take of the alloyed gold you are using, 1 pennyweight; fine silver, 6 grains.
X.—Alloy for Dry Colored Rings.—Fine gold, 1 ounce; fine silver, 4 pennyweights, 6 grains; fine copper, 4 pennyweights, 6 grains.
XI.—Solder.—Scrap gold, 2 ounces; fine silver, 3 pennyweights; fine copper, 3 pennyweights.
XII.—Dry Colored Scrap Reduced to 35s. Gold.—Colored scrap, 1 ounce, 9 pennyweights, 12 grains; fine silver, 2 pennyweights; fine copper, 17 pennyweights, 12 grains; spelter, 4 pennyweights.
«To Quickly Remove a Ring from a Swollen Finger.»—If the ring is of gold, pull the folds of the swollen muscles apart, so that it can be seen, then drop on it a little absolute alcohol and place the finger in a bowl of metallic mercury. In a very few minutes the ring will snap apart. If the ring is of brass, scrape the surface slightly, or put on a few drops of a solution of oxalic acid, or even strong vinegar, let remain in contact for a moment or two, then put into the mercury, and the result will be as before.
«Soldering a Jeweled Ring.»—In order to prevent the bursting of the jewels of a ring while the latter is being soldered, cut a juicy potato into halves and make a hollow in both portions in which the part of the ring having jewels may fit exactly. Wrap the jeweled portion in soft paper, place it in the hollow, and bind up the closed potato with binding wire. Now solder with easy-flowing gold solder, the potato being held in the hand. Another method is to fill a small crucible with wet sand, bury the jeweled portion in the sand, and solder in the usual way.
JEWELRY, TO CLEAN: See Cleaning Preparations and Methods.
«Kalsomine»
Sodium carbonate 8 parts Linseed oil 32 parts Hot water 8 parts White glue 12 parts Whiting 160 parts
Dissolve the sodium carbonate in the hot water, add the oil and saponify by heating and agitation. Cover the glue, broken into small pieces, with cold water and let soak overnight. In the morning pour the whole on a stout piece of stuff and let the residual water drain off, getting rid of as much as possible by slightly twisting the cloth. Throw the swelled glue into a capsule, put on the water bath, and heat gently until it is melted. Add the saponified oil and mix well; remove from the bath, and stir in the whiting, a little at a time, adding hot water as it becomes necessary. When the whiting is all stirred in, continue adding hot water, until a liquid is obtained that flows freely from the kalsomining brush.
The addition of a little soluble blue to the mixture increases the intensity of the white.
«Sizing Walls for Kalsomine.»—A size to coat over “hot walls” for the reception of the kalsomine is made by using shellac, 1 part; sal soda, 1/2 part. Put these ingredients in 1/2 gallon of water and dissolve by steady heat. Another size is made of glue size prepared in the usual way, and alum. To 1/2 pound of white glue add 3/4 pound of alum, dissolving the alum in hot water before adding it to the glue size.
KARATS, TO FIND NUMBER OF: See Jewelers’ Formulas.
KERAMICS: See Ceramics.
KERIT: See Rubber.
KEROCLEAN: See Cleaning Preparations and Methods.
«KEROSENE DEODORIZER:»
See also Benzine, Oils, and Petroleum.
Various processes have been recommended for masking the odor of kerosene such as the addition of various essential {437} oils, artificial oil of mirbane, etc., but none of them seems entirely satisfactory. The addition of amyl acetate in the proportion of 10 grams to the liter (1 per cent) has also been suggested, several experimenters reporting very successful results therefrom. Some years ago Beringer proposed a process for removing sulphur compounds from benzine, which would presumably be equally applicable to kerosene. This process is as follows:
Potassium permanganate 1 ounce Sulphuric acid 1/2 pint Water 3 1/2 pints
Mix the acid and water, and when the mixture has become cold pour it into a 2-gallon bottle. Add the permanganate and agitate until it is dissolved. Then add benzine, 1 gallon, and thoroughly agitate. Allow the liquids to remain in contact for 24 hours, frequently agitating the mixture. Separate the benzine and wash in a similar bottle with a mixture of
Potassium permanganate 1/4 ounce Caustic soda 1/2 ounce Water 2 pints
Agitate the mixture frequently during several hours; then separate the benzine and wash it thoroughly with water. On agitating the benzine with the acid permanganate solution an emulsion-like mixture is produced, which separates in a few seconds, the permanganate slowly subsiding and showing considerable reduction. In the above process it is quite probable that the time specified (24 hours) is greatly in excess of what is necessary, as the reduction takes place almost entirely in a very short time. It has also been suggested that if the process were adopted on a manufacturing scale, with mechanical agitation, the time could be reduced to an hour or two.
KEROSENE-CLEANING COMPOUNDS: See Cleaning Preparations, under Miscellaneous Methods.
KEROSENE EMULSIONS: See Petroleum.
KETCHUP (ADULTERATED), TESTS FOR: See Foods.
KHAKI COLORS: See Dyes.
KID: See Leather.
KISSINGEN SALTS: See Salts (Effervescent).
KISSINGEN WATER: See Waters.
KNIFE-SHARPENING PASTES: See Razor Pastes.
KNOCKENPLOMBE: See Adhesives.
KNOTS: See Paint.
KOLA CORDIAL: See Wines and Liquors.
«KOUMISS SUBSTITUTE:»
See also Beverages.
To prepare a substitute for koumiss from cow’s milk: Dissolve 1/2 ounce grape sugar in 3 fluid ounces water. Mix 18 grains well washed and pressed beer yeast with 2 fluid ounces of cow’s milk. Mix the two liquids in a champagne bottle, fill with milk, stopper securely, and keep for 3 to 4 days at a temperature not exceeding 50° F., shaking frequently. The preparation does not keep longer than 4 to 5 days.
KÜMMEL: See Wines and Liquors.
KWASS: See Beverages.
LABEL PASTES, GLUES, AND MUCILAGES: See Adhesives.
LABEL VARNISHES: See Varnishes.
LACE LEATHER: See Leather.
LACE, TO CLEAN GOLD AND SILVER: See Cleaning Preparations and Methods.
LACES, WASHING AND COLORING OF: See Laundry Preparations.
«Lacquers»
(See also Enamels, Glazes, Paints, Varnishes, and Waterproofing.)
«LAC AND THE ART OF LACQUERING.»
The art of lacquering includes various steps, which are divulged as little as possible. Without them nothing but a varnish of good quality would be realized. Thus in Tonkin, where the abundant {438} production is the object of an important trade with the Chinese, it is so used only for varnishing, while in China the same product from the same sources contributes to most artistic applications.
When the Annamites propose to lacquer an object, a box, for example, they first stop up the holes and crevices, covering all the imperfections with a coating of diluted lac, by means of a flat, close, short brush. Then they cover the whole with a thick coating of lac and white clay. This clay, oily to the touch, is found at the bottom of certain lakes in Tonkin; it is dried, pulverized, and sifted with a piece of fine silk before being embodied with the lac. This operation is designed to conceal the inequalities of the wood and produce a uniform surface which, when completely dry, is rendered smooth with pumice stone.
If the object has portions cut or sunk the clayey mixture is not applied, for it would make the details clammy, but in its place a single, uniform layer of pure lac.
In any case, after the pumicing, a third coating, now pure lac, is passed over the piece, which at this time has a mouse-gray color. This layer, known under the name of _sou lot_, colors the piece a brilliant black. As the lac possesses the remarkable property of not drying in dry air, the object is left in a damp place. When perfectly dried the piece is varnished, and the desired color imparted by a single operation. If the metallic applications are excepted, the lac is colored only black, brown, or red.
The following formulas are in use:
Black.—One part of turpentine is warmed for 20 minutes beyond the fusing point; then poured into 3 parts of lac; at the same time _pheu deu_ (copperas) is added. The mixture is stirred for at least a day, sometimes more, by means of a large paddle.
Maroon.—This is prepared by a process similar to the preceding, replacing half of the copperas by an equal quantity of China vermilion.
Red.—The lac, previously stirred for 6 hours, is mixed with hot oil of _trau_, and the whole is stirred for a day, after which vermilion is added. The latter should be of good quality, so as to have it brilliant and unchangeable.
The operation of lacquering is then ended, but there are parts to be gilded. These are again covered with a mixture of lac and oil of _trau_. When this layer is dry the metallic leaves are applied, which are themselves protected by a coating, composed also of lac and oil of _trau_. All these lac and oil of _trau_ mixtures are carefully filtered, which the natives effect by pressing the liquid on a double filtering surface formed of wadding and of a tissue on which it rests. It can only be applied after several months when the metallic leaf is of gold. In the case of silver or tin the protecting coat can be laid on in a few days. It favorably modifies the white tints of these two metals by communicating a golden color. The hue, at first reddish, gradually improves and acquires its full brilliancy in a few months.
Little information is procurable concerning the processes employed by the Chinese. The wood to be lacquered should be absolutely dry. It receives successive applications, of which the number is not less than 33 for perfect work. When the lac coating attains the thickness of 1/4 of an inch it is ready for the engravers. The Chinese, like the inhabitants of Tonkin, make use of oil of _trau_ to mix with the lac, or oil of _aleurites_, and the greatest care is exercised in the drying of the different layers. The operation is conducted in dim-lighted rooms specially fitted up for the purpose; the moisture is maintained to a suitable extent by systematically watering the earth which covers the walls of this “cold stove.”
«Lacquer for Aluminum.»—Dissolve 100 parts of gum lac in 300 parts of ammonia, and heat the solution for about 1 hour moderately on the water bath. After cooling, the mixture is ready for use. The aluminum to be coated is cleaned in the customary manner. After it has been painted with the varnish, it is heated in the oven to about 572° F. The coating and heating may be repeated.
«Lacquer for Brass.»—
Annatto 1/4 ounce Saffron 1/4 ounce Turmeric 1 ounce Seed lac in coarse powder 3 ounces Alcohol 1 pint
Digest the annatto, saffron, and turmeric in the alcohol for several days, then strain into a bottle containing the seed lac; cork and shake until dissolved.
«Lacquer for Bronze.»—I.—The following process yields a protective varnish for bronze articles and other metallic objects in various shadings, the lacquer produced excelling in high luster and permanency: Fill 40 parts of best pale shellac; 12 parts of pulverized Florentine {439} lake; 30 parts gamboge; and 6 parts of dragon’s blood, likewise powdered, into a bottle and add 400 parts of spirit. Allow this mixture to form a solution preferably by heating the flask on the water bath, to nearly the boiling point of the water, and shaking now and then until all has dissolved. After the cooling pour off the liquid from the sediment, if any is present; this liquid constitutes a lacquer of dark-red color. In a second bottle dissolve in the same manner 24 parts of gamboge in 400 parts of spirit, which affords a lacquer of golden yellow color. According to the desired shade, the red lacquer is now mixed with the yellow one, thus producing any hue required from the deepest red to a golden tone. If necessary, thin with spirit of wine. The varnish is applied, as usual, on the somewhat warmed article, a certain temperature having to be adhered to, which can be ascertained by trials and is easily regulated by feeling.
II.—The following is equally suitable for boots and leather goods as for application on iron, stone, glass, paper, cloth, and other surfaces. The inexperienced should note before making this liquid that it does not give a yellowish bronze like gold paint, but a darkish iridescent one, and as it is a pleasing variation in aids to home decoration, it would doubtless sell well. Some pretty effects are obtained by using a little phloxine instead of part of the violet aniline, or phloxine alone will produce a rich reddish bronze, and a lustrous peacock green is obtained with brilliant aniline green crystals.
Quantities: Flexile methylated collodion, 1 gallon; pure violet aniline, 1 pound. Mix, stand away for a few days to allow the aniline to dissolve and stir frequently, taking care to bung down securely, as the collodion is a volatile liquid, then strain and bottle off. It is applied with a brush, dries rapidly, and does not rub off or peal.
«Celluloid Lacquer.»—Dissolve uncolored celluloid in a mixture of strong alcohol and ether. The celluloid first swells up in the solvent, and after vigorous shaking, the bottle is allowed to stand quietly for the undissolved portion to settle, when the clear, supernatant fluid is poured off. The latter may be immediately used; it yields a colorless glossy lacquer, or may be colored, as desired, with aniline colors.
«Colored Lacquer.»—Make a strong solution of any coloring matter which is soluble in methylated spirit, such as cochineal, saffron, the aniline dyes, etc. Filter through fine cambric, and to this filtered solution add brown shellac in flakes in the proportion of 4 to 5 ounces of shellac to each pint of methylated spirit. Shake once a day for about 8 days. If too thick it may be thinned by adding more colored spirit or plain spirit as required, and any lighter shade can be obtained by mixing with plain lacquer mixed in the above proportions. Lacquer works best in a warm, dry place, and the process is improved by slightly warming the articles, which must be absolutely free from grease, dirt, or moisture. The best results are obtained by applying many coats of thin, light-colored lacquer, each coat to be thoroughly dry before applying the next.
Apply with a soft camel’s-hair brush; it is better to use too small a brush than too large. When complete, warm the articles for a few seconds before a clear fire; the hotter the better; if too hot, however, the colors will fade. This makes the lacquer adhere firmly, especially to metallic surfaces. Aniline green works very well.
«Lacquer for Copper.»—A lacquer which to a certain degree resists heat and acid liquids, but not alkaline ones, is obtained by heating fine, thickly liquid amber varnish, whereby it is rendered sufficiently liquid to be applied with the brush. The copper article is coated with this and left to stand until the lacquer has dried perfectly. Next, the object is heated until the lacquer commences to smoke and turns brown. If the operation is repeated twice, a coating is finally obtained, which, as regards resisting qualities to acid bodies, excels even enamel, but which is strongly attacked even by weakly alkaline liquids.
«Ebony Lacquer.»—The ebony lacquer recommended by the well-known English authority, Mr. H. C. Standage, consists of 1/3 ounce aniline hydrochloride, 1/3 ounce alcohol, 1 part sulphate of copper, 100 parts of water. The aniline dye is dissolved in the alcohol and the copper sulphate in the water. The wood is first coated with the copper sulphate solution, and after this coating has been given plenty of time to dry the aniline salt tincture is applied. Shortly the copper salt absorbed by the wood will react on the aniline hydrochloride, developing a deep, rich black which acids or alkalies are powerless to destroy. Coat with shellac and give a French polish, thus bringing the ebony finish up to a durable and unsurpassed luster. {440}
«GOLD LACQUERS:»
I.—For Brassware.—A gold lacquer to improve the natural color of brassware is prepared from 16 parts gum lac, 4 parts dragon’s blood, and 1 part curcuma powder dissolved in 320 parts spirits of wine in the warmth and filtered well. The articles must be thoroughly cleaned by burning, grinding, or turning either dull or burnished, and then coated with a thin layer of the above mixture, applied with a soft hair brush or a pad of wadding. If the objects are colored the lacquer must be laid on by stippling. Should the color be too dark, it may be lightened by reduction with a little spirit until the correct shade is produced. The most suitable temperature for the metal during the work is about the warmth of the hand; if too hot or too cold, the lacquer may smear, and will then have to be taken off again with spirit or hot potash lye, the goods being dried in sawdust or recleaned as at first, before applying the lacquer again. Round articles may be fixed in the lathe and the lacquer laid on with a pad of wadding. In order to color brassware, a solution of 30 parts caustic soda; 10 parts cupric carbonate; 200 parts water (or 200 parts ammonia neutralized by acetic acid); 100 parts verdigris, and 60 parts sal ammoniac is employed, into which the warmed articles are dipped. After having dried they are coated with colorless shellac varnish.
II.—For Tin.—Transparent gold lacquer for tin (all colors) may be made as follows: Take 1/2 pint of alcohol, add 1 ounce gum shellac; 1/2 ounce turmeric; 1 1/4 ounce red sanders. Set the vessel in a warm place and shake frequently for half a day. Then strain off the liquor, rinse the bottle and return it, corking tightly for use. When this is used, it must be applied to the work freely and flowed on full, or if the work admits it, it may be dipped. One or more coats may be given as the color is required light or dark. For rose color substitute 1/4 ounce of finely ground lake in place of the turmeric. For blue, substitute Prussian blue. For purple, add a little of the blue to the turmeric.
For Bottle Caps, etc.—
I.—Gum gutta 10 parts Shellac 100 parts Turpentine 10 parts Alcohol 450 parts
II.—Gum gutta 40 parts Dragon’s blood 5 parts Alcoholic extract of sandalwood 5 parts Sandarac 75 parts Venice turpentine 25 parts Alcohol, 95 per cent 900 parts
Mix and dissolve by the aid of a gentle heat.
«Liquid Bottle Lac.»—Into a half-gallon bottle put 8 ounces of shellac, and pour over it 1 1/2 pints of alcohol of 94 per cent, and 2 1/2 ounces of sulphuric ether. Let stand, with occasional shaking, until the shellac is melted, and then add 4 ounces of thick turpentine and 1/2 ounce of boric acid. Shake until dissolved. To color, use the aniline colors soluble in alcohol—for red, eosine; blue, phenol blue; black, negrosin; green, aniline green; violet, methyl violet, etc. If it is desired to have the lac opaque, add 8 ounces of pulverized steatite, but remember to keep the lac constantly stirred while using, as otherwise the steatite falls to the bottom.
«Lithographic Lacquer.»—Dissolve 15 parts, by weight, of red lithol R or G in paste of 17 per cent, in 150 parts, by weight, of hot water. Boil for 2 minutes, shaking with 2.5 parts, by weight, of barium chloride. Dissolve in 25 parts, by weight, of water. Add to the mixture 100 parts, by weight, of aluminum hydrate of about 4 per cent. Cool, filter, and dry.
«Lacquer for Microscopes, Mathematical Instruments, etc.»—Pulverize 160 parts, by weight, turmeric root, cover it with 1,700 parts alcohol, digest in a warm place for 24 hours, and then filter. Dissolve 80 parts dragon’s blood, 80 parts sandarac, 80 parts gum elemi, 50 parts gum gutta, and 70 parts seed lac, put in a retort with 250 parts powdered glass, pour over them the colored alcohol first made, and hasten solution by warming in the sand or water bath. When completely dissolved, filter.
«To Fix Alcoholic Lacquers on Metallic Surfaces.»—Dissolve 0.5 parts of crystallized boracic acid in 100 parts of the respective spirit varnish whereby the latter after being applied forms so hard a coating upon a smooth tin surface that it cannot be scratched off even with the finger-nails. The aforementioned percentage of boracic acid should not be exceeded in preparing the solution; otherwise the varnish will lose in intensity of color.
«Lacquer for Oil Paintings.»—Dilute 100 parts of sulphate of baryta with 600 parts of water containing in solution 60 parts of red lithol R or G in paste of 17 {441} per cent. Boil the mixture for several minutes in a solution of 10 parts of barium chloride in 100 parts of water. After cooling, filter and dry.
«Lacquers for Papers.»—I.—With base of baryta: Dissolve 30 parts of red lithol R or G in paste of 17 per cent, in 300 parts of hot water. Add an emulsion obtained by mixing 10 parts of sulphate of alumina in 100 parts of water and 5 parts of calcined soda dissolved in 50 parts of water. Precipitate with a solution of 17.5 parts of barium chloride in 125 parts of water. Cool and filter.
II.—With base of lime: Dissolve 30 parts red lithol R or G in paste of 17 per cent, in 300 parts of hot water. Boil for a few minutes with an emulsion prepared by mixing 10 parts sulphate of alumina with 100 parts of water and 2.5 parts of slaked lime in 100 parts of water. Filter after cooling.
«Lacquer for Stoves and other Articles to Withstand Heat.»—This is not altered by heat, and does not give off disagreeable odors on heating: Thin 1 part of sodium water glass with 2 parts of water in order to make the vehicle. This is to be thickened with the following materials in order to get the desired color: White, barium sulphate or white lead; yellow, baryta chromate, ocher, or uranium yellow; green, chromium oxide or ultramarine green; brown, cadmium oxide, manganese oxide, or sienna brown; red, either iron or chrome red. The coloring materials must be free from lumps, and well ground in with the vehicle. Bronze powders may also be used either alone or mixed with other coloring stuffs, but care must be taken, in either instance, to secure a sufficient quantity. The colors should be made up as wanted, and no more than can conveniently be applied at the time should be prepared. An excellent way to use the bronze powders is to lay on the coloring matter, and then to dust on the powder before the glass sets. Lines or ornamentation of any sort may be put on by allowing the coating of enamel to dry, and then drawing the lines or any desired design with a fresh solution of the water glass colored to suit the taste, or dusted over with bronze.
«MISCELLANEOUS RECIPES:»
«Russian Polishing Lac.»—
I.—Sticklac 925 parts Sandarac 875 parts Larch turpentine 270 parts Alcohol, 96 per cent 3,500 parts
The sticklac is broken up and mixed with the sandarac, put into a suitable container with a wide mouth, the spirit poured over it and set aside. After standing for a week in a warm place, frequently stirring in the meantime (best with a glass rod) and fully dissolving, stir in the turpentine. Let stand 2 or 3 days longer, then filter through glass wool. The sandarac dissolves completely in the spirit, but the stick leaves a slight residue which may be added to the next lot of lac made up and thus be treated to a fresh portion of spirit. The larch turpentine should be of the best quality. This lac is used by woodcarvers and turners and is very much prized by them.
«Mastic Lac.»—
II.—Mastic, select 150 parts Sandarac 400 parts Camphor 15 parts Alcohol, 96 per cent 1,000 parts
Prepare as directed in the first recipe.
«Leather Polish Lac.»—
III.—Shellac 16 parts Venice turpentine 8 parts Sandarac 4 parts Lampblack, Swedish 2 parts Turpentine oil 4 parts Alcohol, 96 per cent 960 parts
The alcohol and turpentine oil are mixed and warmed under constant stirring in the sand or water bath. The shellac and sandarac are now stirred in, the stirring being maintained until both are dissolved. Finally add the turpentine and dissolve. Stir the lampblack with a little vinegar and then add and stir in. Instead of lampblack 125 to 150 parts of nigrosin may be used. This lac should be well shaken before application.
LACQUERED WARE, TO CLEAN: See Cleaning Preparations and Methods.
LAKES: See Dyes.
«LAMPBLACK:»
Production of Lampblack.—The last oil obtained in the distillation of coal tar, and freed from naphthalene as far as possible, viz., soot oil, is burned in a special furnace for the production of various grades of lampblack. In this furnace is an iron plate, which must always be kept glowing; upon this plate the soot oil trickles through a small tube fixed above it. It is decomposed and {442} the smoke (soot) rises into four chambers through small apertures. When the quantity of oil destined for decomposition has been used up, the furnace is allowed to stand undisturbed for a few days, and only after this time has elapsed are the chambers opened by windows provided for that purpose. In the fourth chamber is the very finest lampblack, which the lithographers use, and in the third the fine grade employed by manufacturers of printers’ ink, while the first and second contain the coarser soot, which, well sifted, is sold as flame lampblack.
From grade No. 1 the calcined lampblack for paper makers is also produced. For preparing this black capsules of iron plate with closing lid are filled, the stuff is stamped firmly into them and the cover smeared up with fine loam. The capsules are next placed in a well drawing stove and calcined, whereby the empyreumatic oils evaporate and the remaining lampblack becomes odorless. Allow the capsules to cool for a few days before opening them, as the soot dries very slowly, and easily ignites again as soon as air is admitted if the capsules are opened before. This is semi-calcined lampblack.
For the purpose of preparing completely calcined lampblack, the semi-calcined article is again jammed into fresh capsules, closing them up well and calcining thoroughly once more. After 2 days the capsules are opened containing the all-calcined lampblack in compact pieces.
For the manufacture of coal soot another furnace is employed. Asphalt or pitch is burned in it with exclusion of air as far as practicable. It is thrown in through the doors, and the smoke escapes through the chimney to the soot chambers, 1, 2, 3, 4, and 5, assorting itself there.
When the amount of asphalt pitch destined for combustion has burned up completely, the furnace is left alone for several days without opening it. After this time has elapsed the outside doors are slowly opened and some air is admitted. Later on they can be opened altogether after one is satisfied that the soot has cooled completely. Chamber 4 contains the finest soot black, destined for the manufacture of leather cloth and oil cloth. In the other chambers is fine and ordinary flame black, which is sifted and packed in suitable barrels. Calcined lampblack may also be produced from it, the operation being the same as for oil black.
LAMP BURNERS AND THEIR CARE: See Household Formulas.
«LAMPS:»
«Coloring Incandescent Lamps.»—Incandescent light globes are colored by dipping the bulbs into a thin solution of collodion previously colored to suit with anilines soluble in collodion. Dip and rotate quickly, bulb down, till dry.
For office desks, room lights, and in churches, it appears often desirable to modify the glaring yellowish rays of the incandescent light. A slight collodion film of a delicate bluish, greenish, or pink shade will do that.
For advertising purposes the bulbs are often colored in two or more colors. It is also easy with a little practice to paint words or pictures, etc., on the bulbs with colored collodion with a brush.
Another use of colored collodion in pharmacy is to color the show globes on their inside, thus avoiding freezing and the additional weight of the now used colored liquids. Pour a quantity of colored collodion into the clean, dry globe, close the mouth and quickly let the collodion cover all parts of the inside. Remove the balance of the collodion at once, and keep it to color electric bulbs for your trade.
LANOLINE CREAMS: See Cosmetics.
LANOLINE SOAP: See Soap.
LANTERN SLIDES: See Photography.
«LARD:»
«Detection of Cottonseed Oil in Lard.»—Make a 2 per cent solution of silver nitrate in distilled water, and acidify it by adding 1 per cent of nitrate acid, C. P. Into a test tube put a sample of the suspected lard and heat gently until it liquefies. Now add an equal quantity of the silver nitrate solution, agitate a little, and bring to a boil. Continue the boiling vigorously for about 8 minutes. If the lard remain clear and colorless, it may be accepted as pure. The presence of cottonseed oil or fat will make itself known by a coloration, varying from yellow, grayish green to brown, according to the amount present.
LATHE LUBRICANT: See Lubricants. {443}
LAUNDRY INKS: See Household Formulas.
«Laundry Preparations»
«BLUING COMPOUNDS:»
«Laundry Blue.»—The soluble blue of commerce, when properly made, dissolves freely in water, and solutions so made are put up as liquid laundry blue. The water employed in making the solution should be free from mineral substances, especially lime, or precipitation may occur. If rain water or distilled water and a good article of blue be used, a staple preparation ought apparently to result; but whether time alone affects the matter of solubility it is impossible to state. As it is essential that the solution should be a perfect one, it is best to filter it through several thicknesses of fine cotton cloth before bottling; or if made in large quantities this method may be modified by allowing it to stand some days to settle, when the top portion can be siphoned off for use, the bottom only requiring filtration.
This soluble blue is said to be potassium ferri-ferrocyanide, and is prepared by gradually adding to a boiling solution of potassium ferricyanide (red prussiate of potash) an equivalent quantity of hot solution of ferrous sulphate, boiling for 2 hours and washing the precipitate on a filter until the washings assume a dark-blue color; the moist precipitate can then at once be dissolved by the further addition of a sufficient quantity of water. About 64 parts of the iron salt are necessary to convert 100 parts of the potassium salt into the blue compound.
Leaf bluing for laundry use may be prepared by coating thick sized paper with soluble blue formed into a paste with a mixture of dextrin mucilage and glycerine. Dissolve a given quantity of dextrine in water enough to make a solution about as dense as ordinary syrup, add about as much glycerine as there was dextrine, rub the blue smooth with a sufficient quantity of this vehicle and coat the sheets with the paint. The amount of blue to be used will depend of course on the intended cost of the product, and the amount of glycerine will require adjustment so as to give a mixture which will not “smear” after the water has dried out and yet remain readily soluble.
Ultramarine is now very generally used as a laundry blue where the insoluble or “bag blue” is desired. It is mixed with glucose, or glucose and dextrine, and pressed into balls or cakes. When glucose alone is used, the product has a tendency, it is said, to become soft on keeping, which tendency may be counteracted by a proper proportion of dextrin. Bicarbonate of sodium is added as a “filler” to cheapen the product, the quantity used and the quality of the ultramarine employed being both regulated by the price at which the product is to sell.
The coal-tar or aniline blues are not offered to the general public as laundry blues, but laundry proprietors have them frequently brought under their notice, chiefly in the form of solutions, usually 1 to 1 1/2 per cent strong. These dyes are strong bluing materials, and, being in the form of solution, are not liable to speck the clothes. Naturally their properties depend upon the particular dye used; some are fast to acids and alkalies, others are fast to one but not to another; some will not stand ironing, while others again are not affected by the operation; generally they are not fast to light, but this is only of minor importance. The soluble, or cotton, blues are those most favored; these are made in a great variety of tints, varying from a reddish blue to a pure blue in hue, distinguished by such brands as 3R, 6B, etc. Occasionally the methyl violets are used, especially the blue tints. Blackley blue is very largely used for this purpose, being rather faster than the soluble blues. It may be mentioned that a 1 per cent solution of this dye is usually strong enough. Unless care is taken in dissolving these dyes they are apt to produce specks. The heat to which the pure blues are exposed in ironing the clothes causes some kinds to assume a purple tinge.
The cheapest aniline blue costs about three times as much as soluble blue, yet the tinctorial power of the aniline colors is so great that possibly they might be cheapened.
«Soluble Blue.»—I.—Dissolve 217 parts of prussiate of potash in 800 parts of hot water and bring the whole to 1,000 parts. Likewise dissolve 100 parts of ferric chloride in water and bring the solution also to 1,000 parts. To each of these solutions add 2,000 parts of cooking salt or Glauber’s salt solution saturated in the cold and mix well. The solutions thus prepared of prussiate of potash and ferric chloride are now mixed together with stirring. Allow to settle and remove by suction the clear liquid containing undecomposed ferrocyanide of {444} potassium and Glauber’s salt; this is kept and used for the next manufacture by boiling it down and allowing the salts to crystallize out. The percentage of ferrocyanide of potassium is estimated by analysis, and for the next production proportionally less is used, employing that obtained by concentration.
After siphoning off the solution the precipitate is washed with warm water, placed on a filter and washed out on the latter by pouring on cold water until the water running off commences to assume a strong blue color. The precipitate is then squeezed out and dried at a moderate heat (104° F.). The Paris blue thus obtained dissolves readily in water and can be extensively employed in a similar manner as indigo carmine.
II.—Make ordinary Prussian blue (that which has been purified by acids, chlorine, or the hypochlorites) into a thick paste with distilled or rain water, and add a saturated solution of oxalic acid sufficient to dissolve. If time be of no consequence, by leaving this solution exposed to the atmosphere, in the course of 60 days the blue will be entirely precipitated in soluble form. Wash with weak alcohol and dry at about 100° F. The resultant mass dissolves in pure water and remains in solution indefinitely. It gives a deep, brilliant blue, and is not injurious to the clothing or the hands of the washwoman.
The same result may be obtained by precipitating the soluble blue from its oxide solution by the addition of alcohol of 95 per cent, or with a concentrated solution of sodium sulphate. Pour off the mother liquid and wash with very dilute alcohol; or throw on a filter and wash with water until the latter begins to come off colored a deep blue.
«Liquid Laundry Blue.»—This may be prepared either with liquid Prussian blue or indigo carmine. Make a solution of gum dragon (gum tragacanth) by dissolving 1 to 2 ounces of the powdered gum in 1 gallon of cold water in which 1/2 ounce oxalic acid has been dissolved. The gum will take several days to dissolve, and will require frequent stirring and straining before use. To the strained portion add as much Prussian blue in fine powder as the liquid will dissolve without precipitating, and the compound is ready for use.
Instead of powdered Prussian blue, soluble Prussian blue may be used. This is made by dissolving solid Prussian blue in a solution of oxalic acid, but as the use of oxalic acid is to be deprecated for the use of laundresses, as it would set up blood poisoning should it get into any cuts in the flesh, it is best to prepare liquid blue by making a solution of yellow prussiate of potash (ferrocyanide of potassium) with water, and then by adding a sufficient quantity of chloride of iron to produce a blue, but not enough to be precipitated.
«Ball Blue.»—The ball sold for laundry use consists usually, if not always, of ultramarine. The balls are formed by compression, starch or some other excipient of like character being added to render the mass cohesive. Blocks of blue can, of course, be made by the same process. The manufacturers of ultramarine prepare balls and cubes of the pigment on a large scale, and it does not seem likely that there would be a sufficient margin of profit to justify the making of them in a small way from the powdered pigment. Careful experiments, however, would be necessary to determine this positively. Ultramarine is of many qualities, and it may be expected that the balls will vary also in the amount of “filling” according to the price at which they are to be sold.
Below is a “filled” formula:
Ultramarine 6 ounces Sodium carbonate 4 ounces Glucose 1 ounce Water, a sufficient quantity.
Make a thick paste, roll into sheets, and cut into tablets. The balls in bulk can be obtained only in large packages of the manufacturers, say barrels of 200 pounds; but put up in 1-pound boxes they can be bought in cases as small as 28 pounds.
«Laundry Blue Tablets.»—
Ultramarine 6 ounces Sodium carbonate 4 ounces Glucose 1 ounce Water, a sufficient quantity.
Make a thick paste, roll into sheets, and cut into tablets.
«Polishes or Glazes for Laundry Work.»—I.—To a mixture of 200 parts each of Japan wax and paraffine, add 100 parts of stearic acid, melt together, and cast in molds. If the heated smoothing iron be rubbed with this wax the iron will not merely get over the surface much more rapidly, but will leave a handsome polish.
«Laundry Gloss Dressing.»—
II.—Dissolve white wax, 5.0 parts, in ether, 20.5 parts, and add spirit, 75.0 parts. Shake before use.
Heat until melted, in a pot, 1,000 parts {445} of wax and 1,000 parts of stearine, as well as a few drops of an essential oil. To the hot liquid add with careful stirring 250 parts of ammonia lye of 10 per cent, whereby a thick, soft mass results immediately. Upon further heating same turns thin again, whereupon it is diluted with 20,000 parts of boiling water, mixed with 100 parts of starch and poured into molds.
«STARCHES.»
Most laundry starches now contain some polishing mixture for giving a high luster.
I.—Dissolve in a vessel of sufficient capacity, 42 parts of crystallized magnesium chloride in 30 parts of water. In another vessel stir 12 parts of starch in 20 parts of water to a smooth paste. Mix the two and heat under pressure until the starch is fluidified.
II.—Pour 250 parts, by weight, of water, over 5 parts, by weight, of powdered gum tragacanth until the powder swells uniformly; then add 750 parts, by weight, of boiling water, dissolve 50 parts, by weight, of borax in it, and stir 50 parts, by weight, of stearine and 50 parts, by weight, of talcum into the whole. Of this fluid add 250 parts to 1,000 parts of boiled starch, or else the ironing oil is applied by means of a sponge on the starched wash, which is then ironed.
By weight
III.—Starch 1,044 parts Borax 9 parts Common salt 1 part Gum arabic 8 parts Stearine 20 parts
«WASHING FLUIDS, BRICKS AND POWDERS:»
«Washing Fluids.»—Rub up 75 parts of milk of sulphur with 125 parts of glycerine in a mortar, next add 50 parts of camphorated spirit and 1 part of lavender oil, and finally stir in 250 parts of rose water and 1,000 parts of distilled water. The liquid must be stirred constantly when filling it into bottles, since the sulphur settles rapidly and would thus be unevenly distributed.
«Grosser’s Washing Brick.»—
Water 54 parts Sodium hydrate 38.21 parts Sodium biborate 6.61 parts Sodium silicate 1.70 parts
«Haenkel’s Bleaching Solution.»—
Water 36.15 parts Sodium hydrate 40.22 parts Sodium silicate 23.14 parts
«Luhn’s Washing Extract.»—
Water 34.50 parts Sodium hydrate 25.33 parts Soap 39.40 parts
«Washing Powders.»—
I.—Sodium carbonate, partly effloresced 2 parts Soda ash 1 part
II .—Sodium carbonate, partly effloresced 6 parts Soda ash 3 parts Yellow soap 1 part
III .—Sodium carbonate, partly effloresced 3 parts Soap bark 1 part
IV .—Sodium carbonate, partly effloresced 1 part Borax 1 part Yellow soap 1